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Citation: Guo Guolin, Pan Zuohua, Zhang Zeying. THE CRYSTAL AND MOLECULAR STRUCTURE OF DIETHYL ETHER TETRACHLORIDE TITANIUM[J]. Acta Physico-Chimica Sinica, ;1986, 2(03): 278-283. doi: 10.3866/PKU.WHXB19860314 shu

THE CRYSTAL AND MOLECULAR STRUCTURE OF DIETHYL ETHER TETRACHLORIDE TITANIUM

1.
Laboratory of structure of matter, Institute of physical chemistry, Peking University

Received Date: 25 December 1984
Available Online: 15 June 1986

The crystal and molecular structure of titanium ether complex has been determined by X-ray diffraction. TiCl_4 and Et_2O can form 1:2 complex, TiCl_4·2Et_2O, which is in cis-configuration. The crystal belongs to monoclinic space group C_(2h)~5P21/n with unit cell parameters: a=0.8877(4) nm, b=1.3115(8) nm, c=1.3437(8) nm, β=98.27(5)°, Z=4. The structure was refined to R_1=0.108、R_2=0.127 for 1002 reflections.
It has been showed that the titanium ether complex which has been used to modify the catalyst (3TICl_3·AlCl_3) is TiCl_4·2Et_2O. The powder pattern and infrared spectra of the complex have also been t. Some bases for characterizing the catalyst have provided.
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