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Citation: Guo Guolin, Xie Youchang. ALUMINUM-27 AND PROTON NMR SPECTROSCOPY OF THE ALUMINUM ETHER COMPLEX[J]. Acta Physico-Chimica Sinica, ;1985, 1(05): 397-403. doi: 10.3866/PKU.WHXB19850501 shu

ALUMINUM-27 AND PROTON NMR SPECTROSCOPY OF THE ALUMINUM ETHER COMPLEX

Guo Guolin ,
Xie Youchang

1.
Laboratory for Structure of Matter, Institute of Physical Chemistry, Peking University

Received Date: 4 October 1984
Available Online: 15 October 1985

The chemical shifts and linewidths for aluminum chloride in ethyl ether have been studied by O'Reilly~[1], Haragushi~[2] and Kidd. But-different values have been reported. Up to now the divergence of shifts and linewidths is still present on this question.
In studying the Ziegler-Natta catalyst, the ~(27)Al NMR datum of AlCl_3 Et_2O complex are very important. So we must re-examine them.
It has been verified that the chemical shifts and Iinewidths of the complex in ether are 100.9 ppm and 125Hz respectively, and no...
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