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Citation: Wang Honghui, Zhu Daoben, Zhu Naijue, Fu Heng. CRYSTAL STRUCTURES OF TETRABUTYLAMMONIUM BIS(ISOTRITHIONEDITHIOLATO) COPPER (Ⅱ) AND ZINC (Ⅱ)[J]. Acta Physico-Chimica Sinica, ;1985, 1(04): 378-383. doi: 10.3866/PKU.WHXB19850413 shu

CRYSTAL STRUCTURES OF TETRABUTYLAMMONIUM BIS(ISOTRITHIONEDITHIOLATO) COPPER (Ⅱ) AND ZINC (Ⅱ)

1.
Institute of Chemistry, Academia Sinica, Beijing

Received Date: 25 December 1984
Available Online: 15 August 1985

The crystal structures of the title compounds have been determined from threedimensional intensity measured on a R3m/E four circle diffractometer. The crystallographic data are listed in Table 1.
The structure of [N(C_4H_9)_4]_2[Cu(S_5C_3)_2] was solved by trial and error using isomophous [N(C_4H_9)_4]_2[Pd(S_5C_3)_2] crystal data. The structure of [N(C_4H_9)_4]_2[Zn(S_5C_3)_2] was solved by direct method using SHELXTL program system. The H atom coordinates were calculated geometrically. The refinement of coordinates and anisotropic thermal parameters was performed by “blocked cascade” least squares to R=0.044 for Cu(II) compound and R=0.057 for Zn(II) compound calculated on the basis of 2424 and 1219 independent reflections respectively. All the numerical calculations were carried out on a Eclipse/S_(140) computer with programs of R3m/E system.
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