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Citation: Chao Jianping, Dai Ming. STUDIES ON THERMODYNAMIC PROPERTIES OFBINARY SYSTEMS CONTAINING ALCOHOLS
Ⅱ. EXCESS ENTHALPIES OF C₁ TO C₅ NORMAL ALCOHOLS+1,4-DIOXANE[J]. Acta Physico-Chimica Sinica, ;1985, 1(03): 213-214. doi: 10.3866/PKU.WHXB19850304 shu

STUDIES ON THERMODYNAMIC PROPERTIES OFBINARY SYSTEMS CONTAINING ALCOHOLS
Ⅱ. EXCESS ENTHALPIES OF C₁ TO C₅ NORMAL ALCOHOLS+1,4-DIOXANE

Chao Jianping ,
Dai Ming

1.
Research Laboratory of Solution Chemistry; Henan Institute of Chemistry; Zheng Zhon; China

Received Date: 10 January 1985
Available Online: 15 June 1985

The molar execess enthalpies of C_1 to C_5 normal alcohols with 1,4-dioxane have been measured with a Picker flow microcalorimeter. From our measurements we can come to the following results. Mixing n-alcohols with 1,4-dioxane are all endothermic processes. The maximum values of H~E are situated near 0.49 mole fraction of n-alcohols. H~E of these systems increase with increasing chain length of the alcohols, whereas the increments for two neighbour-alcohols decrease with increasing the number of carbon.
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STUDIES ON THERMODYNAMIC PROPERTIES OFBINARY SYSTEMS CONTAINING ALCOHOLS Ⅱ. EXCESS ENTHALPIES OF C1 TO C5 NORMAL ALCOHOLS+1,4-DIOXANE

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STUDIES ON THERMODYNAMIC PROPERTIES OFBINARY SYSTEMS CONTAINING ALCOHOLS
Ⅱ. EXCESS ENTHALPIES OF C₁ TO C₅ NORMAL ALCOHOLS+1,4-DIOXANE