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Citation: Huang Minhai, Ye Mingku, Tian Zhaowu. POLYACETYLENE FILM FORMED BY ELECTROCHEMICAL TECHNIQUE[J]. Acta Physico-Chimica Sinica, ;1985, 1(02): 193-195. doi: 10.3866/PKU.WHXB19850211 shu

POLYACETYLENE FILM FORMED BY ELECTROCHEMICAL TECHNIQUE

1.
Institute of Physical Chemistry; Xiamen University; Xiamen; Fujian; China

Received Date: 26 June 1984
Available Online: 15 April 1985

The suitably doped polyacetylene film can be used for the conversion of sun- light energy into electrical or chemical energy. A new electrochemical technique was introduced for obtaining polyacetylene film by cathodic initiation of the poly- merization process. The advantage of this technique is that the polymerization process can be controlled by the wave form of electrode current and the composi- tion of the solution. Polyacetylene films of different properties and thickness can be conveniently prepared in this way.
The catalyst was dissolved in certain organic solvent and introduced into the electrolytic cell. The solution was then cooled down to low temperature and saturated with acetylene gas before cathodic polymerization. Several transition metals and other electric conducting materials have been used as electrodes. On passing suitable current, red color appeared at the cathode/solution interface and the polyacetylene film formed gradually.
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