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Citation: Hu Xuezheng, Zhang Youmin, Huang Ziqing. SOLVATION OF n-BUTANE、n-BUTENE-1、BUTADIENE-1,3 IN DIPOLAR APROTIC SOLVENTS AND PROTIC SOLVENT[J]. Acta Physico-Chimica Sinica, ;1985, 1(02): 130-140. doi: 10.3866/PKU.WHXB19850204 shu

SOLVATION OF n-BUTANE、n-BUTENE-1、BUTADIENE-1,3 IN DIPOLAR APROTIC SOLVENTS AND PROTIC SOLVENT

1.
Department of Chemistry Peking University

Received Date: 30 July 1984
Available Online: 15 April 1985

The molar heats of solution of gaseousn-Butane, n-Butene-1 and Butadiene-1,3 in 4 pure dipolar aprotic solvents (dimethylformamide, dimethy sulfoxide, propylene carbonate and N-methy-2-pyrrolidone) and in a protic solvent(methanol) have been calorimetrically determined at 298.15 K and 1 atm(Table 3).
The calorimetric measurements were made by expansive calorimeter, the sensi- tivity was 0.01 cal. The solute molarities were all below 0.04. The measurements of solute content were made by gas chromatography.
The theoriti...
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