Citation: Xunzhang Fan, Yuanjin Zhao, Shufang Luo, Aihua He. Karl Ziegler: A Pioneer in the Polyolefin Industry – Commemorating the 50th Anniversary of the German Chemist’s Passing[J]. University Chemistry, ;2024, 39(8): 389-394. doi: 10.3866/PKU.DXHX202312065 shu

Karl Ziegler: A Pioneer in the Polyolefin Industry – Commemorating the 50th Anniversary of the German Chemist’s Passing

Shandong Provincial Key Laboratory of Olefin Catalysis and Polymerization, Key Laboratory of Rubber-Plastics (Ministry of Education), School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, Shandong Province, China

Received Date: 19 December 2023
Revised Date: 13 March 2024

This article commemorates the 50th anniversary of the passing of Karl Ziegler, a Nobel Prize-winning German chemist, by exploring his scientific journey and remarkable contributions. Ziegler’s unwavering passion for science, unique thinking, and exceptional experimental skills formed the bedrock of his scientific endeavors. His research primarily focused on free radical compounds, polycyclic compounds, and organometallic compounds. The Ziegler-Natta catalyst, which he co-invented and named alongside Giulio Natta, had far-reaching implications for the global polyolefin industry, giving rise to a market worth billions of dollars.
- Karl Ziegler,
- Ziegler-Natta catalyst,
- Biography
1. [1]
  Kanellopoulos, V.; Kiparissides, C. Multimodal Polymers with Supported Catalysts: Design and Production; 1st ed.; Springer Nature Switzerland AG: Switzerland, 2019; pp. 155–203.
2. [2]
  Ricci, G.; Pampaloni, G.; Sommazzi, A.; Masi, F. Macromolecules 2021, 54 (13), 5879.
3. [3]
  Ziegler, K.; Holzkamp, E.; Breil, H.; Martin, H. Angew. Chem. 1955, 67 (19–20), 541.
4. [4]
  Böhm, L. Chem. Ing. Tech. 1984, 56 (9), 674.
5. [5]
  Eisch, J. J. J. Chem. Educ. 1983, 60 (12), 1009.
6. [6]
  Kapischke, M.; Pries, A. Surgery 2014, 155 (2), 347.
7. [7]
  Sivaram, S. Resonance 2017, 22, 985.
8. [8]
  Eisch, J. J. Organometallics 2012, 31 (14), 4917.
9. [9]
  Ziegler, K.; Boye, E. Justus Liebigs Annalen Der Chemie 1927, 458 (1), 229.
10. [10]
  Oesper, R. E. J. Chem. Educ. 1948, 4 (9), 78.
11. [11]
  Ziegler, K.; Bähr, K. Berichte Der Deutschen Chemischen Gesellschaft 1928, 61 (2), 253.
12. [12]
  Ziegler, K.; Kleiner, H. Justus Liebigs Annalen Der Chemie 1929, 473 (1), 57.
13. [13]
  Pybus, D. H.; Sell, C. S. The Chemistry of Fragrances: From Perfumer to Consumer, 2nd ed.; Royal Society of Chemistry: UK, 2006; pp. 93–95.
14. [14]
  Ziegler, K.; Eberle, H.; Ohlinger, H. Justus Liebigs Annalen Der Chemie 1933, 504 (1), 94.
15. [15]
  Bawn, C. E. H. Biographical Memoirs of Fellows of the Royal Society 1975, 21, 569.
16. [16]
  Ziegler, K.; Colonius, H. Justus Liebigs Annalen Der Chemie 1930, 479 (1), 135.
17. [17]
  Ziegler, K.; Gellert, H. G. Justus Liebigs Annalen Der Chemie 1950, 567 (1), 195.
18. [18]
  Kauffman, G. B. J. Chem. Educ. 1986, 63, A181
19. [19]
  Martin, H. Polymers, Patents, Profits: A Classic Case Study for Patent Infighting, 1st ed.; Wiley-Vch Verlag GmbH & Co.KGaA: Weinheim, Germany, 2007; pp. 1–33.
20. [20]
  Ziegler, K.; Breil, H.; Holzkamp, E.; Martin, H. Verfahren zur Herstellung von hochmolekularen Polyaethylenen. Ger. Pat. Appl. 973626C, 1960.
21. [21]
  Schaffner, K. Angew. Chem. 2003, 115 (26), 3038.
22. [22]
  Ziegler, K. Rubber Chem. Technol. 1965, 38 (1), 23.
23. [23]
  Natta, G. J. Polym. Sci. Pol. Chem. 1996, 34 (3), 321.
24. [24]
  Hoffmann, R. W. Angew. Chem. Int. Edit. 2001, 40 (8), 1411.
25. [25]
  Norio, K.; Tadaichi, T.; Hiroshi, F. Process for the polymerization and/or copolymerization of olefins with the use of ziegler-type catalysts supported on carrier. US. Pat. Appl. 3642746A, 1972.
26. [26]
  Sun-Chueh, K.; John, K. F. Katalysator zur Regulierung der Molekulargewichtsverteilung von Äthylenpolymeren. Eur. Pat. Appl. 0349927A2, 1990.
27. [27]
  Zheng, W. P.; Ma, Y. P.; Du, D. L.; He, A. H.; Shao, H. F.; Liu, C. G. Chinese J. Polym. Sci. 2021, 39 (1), 70.
28. [28]
  Härkönen, M.; Seppälä, J. V.; Väänänen, T. Studies in Surface Science and Catalysis 1990, 56, 87.
29. [29]
  Sacchi, M. C.; Tritto, I.; Shan, C. J.; Mendichi, R.; Noristi, L. Macromolecules 1991, 24 (26), 6823.
30. [30]
  Cecchin, G.; Morini, G.; Pelliconi, A. Macromolecular Symposia 2001, 173 (1), 195.
31. [31]
  Zheng, W. P.; Zhao, Y. J.; Han, M. C.; Zhou, C. S.; He, A. H. Polymer 2021, 228, 123925.
32. [32]
33. [33]
  Sinn, H.; Kaminsky, W.; Vollmer, H.; Woldt, R. Angew. Chem. Int. Edit. 1980, 19 (5), 390.
34. [34]
  Niu, Q. T.; Zhang, J. Y.; He, A. H. Polym. Int. 2021, 70 (10), 1449.
35. [35]
  Niu, Q. T.; Zhang, J. Y.; Peng, W.; Fan, Z. Q.; He, A. H. Mol. Catal. 2019, 471, 1.
36. [36]
  Han, M. C.; Zhao, Y. J.; Luo, S. F.; Fan, X. Z.; He, A. H. Mol. Catal. 2023, 537, 112938.
37. [37]
  Galli, P.; Vecellio, G. Prog. Polym. Sci. 2001, 26 (8), 1287.
38. [38]
  Dong, K. X.; Zhang, J. Y.; He, A. H. Polymer 2021, 235, 124231.
39. [39]
  Busico, V.; Causà, M.; Cipullo, R.; Credendino, R.; Cutillo, F.; Friederichs, N.; Lamanna, R.; Segre, A.; Castelli, V. V A. J. Phys. Chem. C 2008, 112 (4), 1081.
40. [40]
  Liang, P.; Li, W.; Chen, Y. M.; Dong, C. D.; Zhou, Q.; Feng, Y. R.; Chen, M.; Dai, J. C.; Ren, C. J.; Jiang, B. B.; et al. ACS Catal. 2021, 11 (8), 4411.
41. [41]
  Peng, W.; Xie, J. M.; Zhang, J. Y.; Yang, X.; He, A. H. Mol. Catal. 2020, 494, 111110.
42. [42]
  Xie, J. M.; Tan, X. S.; Peng, W.; Yang, X.; He, A. H. Mol. Catal. 2021, 502, 111399.
43. [43]
  D’Amore, M.; Taniike, T.; Terano, M.; Ferrari, M. A. Materials 2022, 15 (3), 909.
44. [44]
  Wilke, G. Angew. Chem. Int. Edit. 2003, 42 (41), 5000.
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