Citation: Dan Li, Hui Xin, Xiaofeng Yi. Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production[J]. University Chemistry, ;2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046 shu

Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production

Dan Li ¹ ,
Hui Xin ² ,
Xiaofeng Yi ¹

1.
College of Chemistry, Sichuan University, Chengdu 610064, China;
2.
Analytical Testing Center, Sichuan University, Chengdu 610064, China

Received Date: 12 December 2023
Revised Date: 10 January 2024

This study outlines the design of a comprehensive chemical experiment to synthesize Ni-based nanocatalysts with varying grain sizes for biofuel production. Ni/CeO₂、Ni/CeO₂-SiO₂and Ni/SiO₂ nanomaterials were prepared via a conventional impregnation method and characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). The integrated scientific training process—from catalyst synthesis and structural characterization to performance evaluation—not only cultivate students’ comprehensive experimental skills, but also enhance their research literacy. This experiment aims to illuminate the intrinsic relationship between material structure and function, fostering a curiosity for investigating the unknown in the scientific realm. Moreover, the experiment incorporates a curricular focus on the “energy crisis”, heightening students’ awareness of current energy and environmental challenges, and inspiring a personal commitment to environmental stewardship.
- Ni-based catalyst,
- Deoxygenation catalyst,
- Biofuel
1. [1]
2. [2]
  Gosselink, R. W.; Hollak, S. A. W.; Chang, S. W.; Haveren, J. V.; Jong, K. P. D.; Bitter, J. H.; Es, D. S. V. Chem. Sus. Chem. 2013, 6, 1576.
3. [3]
  Hermida, L.; Abdullah, A. Z.; Mohamed, A. R. Renew. Sust. Energy Rev. 2015, 42, 1223.
4. [4]
  Phichitsurathaworn, P.; Choojun, K.; Poo-arporn, Y.; Sooknoi, T. Appl. Catal. A: Gen. 2020, 602, 117644.
5. [5]
  Remón, J.; Casales, M.; Gracia, J.; Callén, M. S.; Pinilla, J. L.; Suelves, I. Chem. Eng. J. 2021, 405, 126705.
6. [6]
  Sushkevich, V. L.; Palagin, D.; Ranocchiari, M.; Van bokhoven, J. A. Science, 2017, 356, 523.
7. [7]
  Wang, Z. J.; Chang, H. H.; Zhang, J.; Sun, Z. H.; Wu, Y. L.; Liu, Y. M.; Zhu, Y. F.; He, H. Y.; Cao, Y.; Bao, X. H. Chem. Commun. 2022, 58 (23), 3779.
8. [8]
  Li, B.; Zhang, B.; Guan, Q.; Chen, S.; Ning, P. Int. J. Hydrog. Energy 2018, 43, 19010.
9. [9]
  Fu, L.; Li, Y.; Cui, H.; Ba, W.; Liu, Y. Appl. Catal. A: Gen. 2021, 623, 118258.
10. [10]
  Yan, C.; Li, H.; Ye, Y.; Wu, H.; Cai, F.; Si, R.; Xiao, J.; Miao, S.; Xie, S.; Yang, F.; et al. Energy Environ. Sci. 2018, 11, 1204.
11. [11]
  Ni, Z.; Djitcheu, X.; Gao, X.; Wang, J.; Liu, H.; Zhang, Q. Sci. Rep. 2022, 12, 5344.
12. [12]
  Mai, H. X.; Sun, L. D.; Zhang, Y. W.; Si, R.; Feng, W.; Zhang, H. P.; Liu, H. C.; Yan, C. H. J. Phys. Chem. B 2005, 109, 24380.
13. [13]
  Zhang, H.; Estudillo-Wong, L. A.; Gao, Y.; Feng, Y.; Alonso-Vante, N. J. Energy Chem. 2021, 59, 615.
14. [14]
  Zeng, Y.; Wang, H.; Yang, H.; Juan, C.; Li, D.; Wen, X.; Zhang, F.; Zhou, J.; Peng, C.; Hu, C. Chin. J. Catal. 2023, 47, 229.
15. [15]
  Gao, S.; Li, Y.; Guo, W.; Ding, X.; Zheng, L.; Wu, L.; Yan, H.; Wang, Y. Mol. Catal. 2022, 533, 112766.
16. [16]
  Jomjaree, T.; Sintuya, P.; Srifa, A.; Koo-amornpattana, W.; Kiatphuengporn, S.; Assabumrungrat, S.; Sudoh, M.; Watanabe, R.; Fukuhara, C.; Ratchahat, S. Catal. Today 2021, 375, 234.
17. [17]
  Hollinger, G. Appl. Surf. Sci. 1981, 8 (3), 318.
18. [18]
  Yan, X.; Hu, T.; Liu, P.; Li, S.; Zhao, B.; Zhang, Q.; Jiao, W.; Chen, S.; Wang, P.; Lu, J.; et al. Appl. Catal. B: Environ. 2019, 246, 221.
19. [19]
  Zhang, B.; Zhang, S.; Liu, B. Appl. Surf. Sci. 2020, 529, 147068.
20. [20]
  Zhang, Y.; Lu, J.; Zhang, L.; Fu, T.; Zhang, J.; Zhu, X.; Gao, X.; He, D.; Luo, Y.; Dionysiou, D. D.; et al. Appl. Catal. B: Environ. 2022, 309, 121249.
21. [21]
  Zhang, Z.; Li, J.; Gao, W.; Ma, Y.; Qu, Y. J. Mater. Chem. A 2015, 3 (35), 18074.
22. [22]
  Zhang, L. J.; Chen, R. H.; Tu, Y.; Gong, X. Y.; Cao, X.; Xu, Q.; Li, Y.; Ye, B. J.; Ye, Y. F.; Zhu, J. F. ACS Catal. 2023, 13 (4), 2202.
23. [23]
  Cheng, Z.; Shan, H.; Sun, Y.; Zhang, L.; Jiang, H.; Li, C. Appl. Surf. Sci. 2020, 513, 145766.
24. [24]
  Li, M.; Amari, H.; van Veen, A. C. Appl. Catal. B: Environ. 2018, 239, 27.
25. [25]
26. [26]
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1.
沈阳化工大学材料科学与工程学院沈阳 110142