稀土金属有机配合物的合成、结构和力致发光性质

引用本文: 陈天云, 肖瑞麟, 顾欣晟, 邵云一, 卢求钧. 稀土金属有机配合物的合成、结构和力致发光性质[J]. 大学化学, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017 shu

Citation: Tianyun Chen, Ruilin Xiao, Xinsheng Gu, Yunyi Shao, Qiujun Lu. Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes[J]. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017 shu

稀土金属有机配合物的合成、结构和力致发光性质

长沙学院生物与化学工程学院, 长沙 410022
基金项目:
国家级大学生创新训练项目(202211077002)；长沙学院科研育人项目

摘要: 力致发光材料因其具有外力作用诱导产生发光的独特性质，其在冲击力、应力、张力或压力等作用力的传感，以及显示、照明、成像等领域具有巨大应用潜力，近年来引起了人们广泛关注。实验以二苯甲酰甲烷(DBM)、Eu(NO₃)₃和三乙胺(TEA)为原料，通过共沉淀法快速合成了离子型Eu³⁺配合物Eu(DBM)₄TEA。采用紫外-可见吸收光谱、红外吸收光谱和X射线衍射谱对配合物的结构进行表征，并测定配合物的荧光性质和力致发光性能。本实验是在现有科研成果的基础上开发的包含稀土金属有机配合物合成、产物仪器表征和产物性能模块化综合化学实验，实现了科教融合；实验原料廉价、实验操作简单，模块化的设计机动灵活，能满足基础实验、综合实验和趣味科普实验等不同层次本科教学需求；实验现象可视，有助于激发学生学习兴趣，提升学生专业认同感。

关键词:

English

Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes

College of Biological and Chemical Engineering, Changsha University, Changsha 410022, China
Received Date: 04 December 2023
Revised Date: 04 February 2024

Abstract: Recently, mechanoluminescence materials have attracted considerable attention due to their unique optical properties induced by external stimulus, demonstrating the excellent potential for sensing impact, stress, tension, pressure, display and lighting, and imaging. Using dibenzoylmethane (DBM), Eu(NO₃)₃, and triethylamine (TEA) as raw materials, the ionic Eu³⁺ coordination complexes Eu(DBM)₄TEA were obtained. The complexes were characterized by UV-vis absorption spectroscopy, infrared spectroscopy, X-ray diffraction, and solid fluorescence. Their mechanoluminescence properties are realized by grinding the sample powder. The designing experiment is developed based on the research results and consists of the synthesis and characterization of lanthanide-based organometallic materials. This experiment with a simple route includes a lot of knowledge and was beneficial to enhance students’ research capabilities, helping students learn the relationship between structure and function, and getting scientific research training.

Key words:

1. [1]
  章文伟, 芦昌盛, 淳远, 俞寿云, 朱成建. 大学化学, 2022, 37, 2108092.
2. [2]
  李厚金陈六平, 张树永. 大学化学, 2022, 37, 2108010.
3. [3]
  Zhuang, Y. X.; Xie, R.-J. Adv. Mater. 2021, 33, 2005925.Zhuang, Y. X.; Xie, R.-J. Adv. Mater. 2021, 33, 2005925.
4. [4]
  Mukherjee, S.; Thilagar, P. Angew. Chem. Int. Ed. 2019, 58, 7922.Mukherjee, S.; Thilagar, P. Angew. Chem. Int. Ed. 2019, 58, 7922.
5. [5]
  Eddingsaas, N. C.; Suslick, K. S. Nature, 2006, 444, 163.Eddingsaas, N. C.; Suslick, K. S. Nature, 2006, 444, 163.
6. [6]
  Hasegawa, Y.; Kitagawa, Y.; Nakanishi, T. NPG Asia Mater. 2018, 10, 52.Hasegawa, Y.; Kitagawa, Y.; Nakanishi, T. NPG Asia Mater. 2018, 10, 52.
7. [7]
  刘明丽, 吴琪, 史慧芳, 安众福, 黄维. 化学学报, 2018, No. 76, 246.
8. [8]
  Hurt, C. R.; McAvoy, N.; Bjorklund, S.; Filipescu, N. Nature 1966, 212, 179.Hurt, C. R.; McAvoy, N.; Bjorklund, S.; Filipescu, N. Nature 1966, 212, 179.
9. [9]
  Wong, H.-Y.; Lo, W.-S.; Chan, W. T. K.; Law, G.-L. Inorg. Chem. 2017, 56, 5135.Wong, H.-Y.; Lo, W.-S.; Chan, W. T. K.; Law, G.-L. Inorg. Chem. 2017, 56, 5135.
10. [10]
  Sweeting, L. M.; Rheingold, A. L. J. Am. Chem. Soc. 1987, 109, 2652.Sweeting, L. M.; Rheingold, A. L. J. Am. Chem. Soc. 1987, 109, 2652.
11. [11]
  Sweeting, L. M. Chem. Mater. 2001, 13, 854.Sweeting, L. M. Chem. Mater. 2001, 13, 854.
12. [12]
  Li, Q. Q.; Li, Z. Acc. Chem. Res. 2020, 53, 962.Li, Q. Q.; Li, Z. Acc. Chem. Res. 2020, 53, 962.
13. [13]
  Chandra, B. P. J. Phys. D: Appl. Phys. 1977, 10, 1531.Chandra, B. P. J. Phys. D: Appl. Phys. 1977, 10, 1531.

扫一扫看文章

计量

PDF下载量: 7
文章访问数: 683
HTML全文浏览量: 119

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

稀土金属有机配合物的合成、结构和力致发光性质

English

Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

稀土金属有机配合物的合成、结构和力致发光性质

English

Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs