Citation: Guang Huang, Lei Li, Dingyi Zhang, Xingze Wang, Yugai Huang, Wenhui Liang, Zhifen Guo, Wenmei Jiao. Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal[J]. University Chemistry, ;2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051 shu

Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal

1.
School of Public Health, Nanjing Medical University, Nanjing 211166, China;
2.
School of Life Sciences and Chemical Engineering, Jiangsu Second Normal University, Nanjing 211200, China

Received Date: 15 November 2023
Revised Date: 28 December 2023

Nickel, prevalently utilized in sectors such as new energy vehicle batteries and electroplating, has brought the environmental challenges, especially in the context of the national dual carbon strategy. The treatment of nickel (Ni²⁺)-enriched wastewater generated by these industries is pivotal for environmental conservation. Traditional Ni²⁺-enriched wastewater treatments, including, ion exchange resins, chemical precipitation, and fluidized bed crystallization granulation technology, often suffer from poor selectivity and the risk of secondary pollution. This study introduces an innovative approach employing a cobalt-based imidazole framework material, ZIF-67, which interacts with Ni²⁺ to form the nickel-cobalt layered double hydroxides (NiCo-LDH), effectively enhancing Ni²⁺ removal. The experiment spans material preparation, characterization, and adsorption performance assessment, supplemented by model analysis and mechanistic investigation. This multifaced approach aims not only to elucidate the adsorption mechanism but also to cultivate students’ research interest, innovative thinking, and practical skills. Tailored for an 8-hour undergraduate comprehensive chemistry laboratory session, this experiment enables students to grasp fundamental principles and analytical methods for Ni²⁺ removal from wastewater. It also solidifies their foundational knowledge, demonstrating the practical application of theoretical concepts in industrial settings. This experiment is designed to bolster students' comprehensive abilities, enhance their scientific literacy, and foster their innovative spirits.
- Imidazolate framework materials,
- Nickel ion,
- Adsorption,
- Comprehensive chemical experiment
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沈阳化工大学材料科学与工程学院沈阳 110142