Citation: Lan Ma, Cailu He, Ziqi Liu, Yaohan Yang, Qingxia Ming, Xue Luo, Tianfeng He, Liyun Zhang. Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes[J]. University Chemistry, ;2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046 shu

Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes

School of Science, Xihua University, Chengdu 610039, China

Received Date: 14 November 2023
Revised Date: 8 January 2024

Surface chemistry permeates various aspects of our daily lives, from the natural phenomenon of the “lotus leaf effect” to the functionalities of specialized industrial products like waterproofing, anti-freezing, and anti-fouling coatings. While these phenomena may seem commonplace and straightforward, they harbor intricate principles of interfacial science. In this experiment, we employ a layer-by-layer self-assembly technique to deposit a hydrophilic coating composed of plant polyphenol tannic acid (TA) and iron (Fe(III)) coordination complex onto the surface of a melt-blown fabric membrane. Subsequent oxidation of catechol groups using sodium periodate (NaIO₄) facilitates the fixation of the polyphenol-metal coordination complex network at the fabric interface, thereby achieving a transition from hydrophobic to hydrophilic modification. Finally, we demonstrate the efficacy of the modified melt-blown fabric membrane in oil-water separation processes. Through this endeavor, we not only showcase the modification process of materials and the resulting property alterations but also delve into the underlying physical and chemical principles layer by layer. The reagents utilized in this educational experiment are environmentally friendly, facilitating simple operation, offering aesthetic appeal, and encouraging interaction. Moreover, the modified membrane boasts recyclability advantages. Employing a gradient approach to science communication, we elucidate the principles and essence behind these phenomena in a comprehensible manner, enabling the public to appreciate the magic and beauty of surface chemistry while acquiring knowledge. This experiment holds promise not only for popular science dissemination and classroom teaching but also for its excellent application prospects.
- Surface chemistry,
- Wetting inversion,
- Membrane materials,
- Metal-polyphenol coordination complex,
- Oil/water separation
1. [1]
2. [2]
  Liu, M. J.; Wang, S. T.; Jiang, L. Nat. Rev. Mater. 2017, 2 (7), 17036.
3. [3]
4. [4]
  Chu, Z. L.; Feng, Y. J.; Seeger, S. Angew. Chem.-Int. Edit 2015, 54 (8), 2328.
5. [5]
  Yang, J.; Wang, L. L.; Xie, A.; Dai, X. H.; Yan, Y. S.; Dai, J. D. Surf. Coat. Technol. 2020, 389, 125630.
6. [6]
  Kim, H. J.; Kim, D.-G.; Yoon, H.; Choi, Y.-S.; Yoon, J. Y.; Lee, J.-C. Adv. Mater. Interfaces 2015, 2 (14), 1500298.
7. [7]
  Zhang, Y. P.; Tong, Y. J.; Shi, L. J.; Miao, C. Q.; Li, W. X. Sep. Purif. Technol. 2022, 303, 122304.
8. [8]
  Jiang, B.; Cheng, K.; Zhang, N.; Yang, N.; Zhang, L. H.; Sun, Y. L. Sep. Purif. Technol. 2021, 255, 117724.
9. [9]
  Rahim, M.; Ejima, H.; Cho, K.; Kempe, K.; Muellner, M.; Best, J.; Caruso, F. Chem. Mater. 2014, 26 (4), 1645.
10. [10]
  Ponzio, F.; Barthes, J.; Bour, J.; Michel, M.; Bertani, P.; Hemmerle, J.; D’Ischia, M.; Ball, V. Chem. Mater. 2016, 28 (13), 4697.
1. [1]
  Zhangshu Wang , Xin Zhang , Jixin Han , Xuebing Fang , Xiufeng Zhao , Zeyu Gu , Jinjun Deng . Exploration and Design of Experimental Teaching on Ultrasonic-Enhanced Synergistic Treatment of Ternary Composite Flooding Produced Water. University Chemistry, 2024, 39(5): 116-124. doi: 10.3866/PKU.DXHX202310056
2. [2]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
3. [3]
  Wenjing ZHANG , Xiaoqing WANG , Zhipeng LIU . Recent developments of inorganic metal complex-based photothermal materials and their applications in photothermal therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2356-2372. doi: 10.11862/CJIC.20240254
4. [4]
  Hong Wu , Yuxi Wang , Hongyan Feng , Xiaokui Wang , Bangkun Jin , Xuan Lei , Qianghua Wu , Hongchun Li . Application of Computational Chemistry in the Determination of Magnetic Susceptibility of Metal Complexes. University Chemistry, 2025, 40(3): 116-123. doi: 10.12461/PKU.DXHX202405141
5. [5]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
6. [6]
  Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, 2024, 39(7): 247-263. doi: 10.3866/PKU.DXHX202310103
7. [7]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
8. [8]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
9. [9]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
10. [10]
  Pengcheng Yan , Peng Wang , Jing Huang , Zhao Mo , Li Xu , Yun Chen , Yu Zhang , Zhichong Qi , Hui Xu , Henan Li . Engineering Multiple Optimization Strategy on Bismuth Oxyhalide Photoactive Materials for Efficient Photoelectrochemical Applications. Acta Physico-Chimica Sinica, 2025, 41(2): 100014-. doi: 10.3866/PKU.WHXB202309047
11. [11]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
12. [12]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
13. [13]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
14. [14]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
15. [15]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
16. [16]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
17. [17]
  Jinfeng Chu , Yicheng Wang , Ji Qi , Yulin Liu , Yan Li , Lan Jin , Lei He , Yufei Song . Comprehensive Chemical Experiment Design: Convenient Preparation and Characterization of an Oxygen-Bridged Trinuclear Iron(III) Complex. University Chemistry, 2024, 39(7): 299-306. doi: 10.3866/PKU.DXHX202310105
18. [18]
  Ruilin Han , Xiaoqi Yan . Comparison of Multiple Function Methods for Fitting Surface Tension and Concentration Curves. University Chemistry, 2024, 39(7): 381-385. doi: 10.3866/PKU.DXHX202311023
19. [19]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
20. [20]
  Xiyuan Su , Zhenlin Hu , Ye Fan , Xianyuan Liu , Xianyong Lu . Change as You Want: Multi-Responsive Superhydrophobic Intelligent Actuation Material. University Chemistry, 2024, 39(5): 228-237. doi: 10.3866/PKU.DXHX202311059

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(61)
HTML views(0)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142