Citation: Qiang Zhou, Pingping Zhu, Wei Shao, Wanqun Hu, Xuan Lei, Haiyang Yang. Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments[J]. University Chemistry, ;2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064 shu

Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments

Qiang Zhou ^1,2 ,
Pingping Zhu ^1,2 ,
Wei Shao ^1,2 ,
Wanqun Hu ^1,2 ,
Xuan Lei ^1,2 ,
Haiyang Yang ¹

1.
School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China;
2.
National Demonstration Center for Experimental Chemistry Education(University of Science and Technology of China), Hefei 230026, China

Received Date: 16 October 2023
Revised Date: 18 December 2023

Currently, the content of 3D printing teaching experiments mostly focuses on introducing students to the basic workflow of 3D printing using commercially available polymers. However, these basic experiments often fail to expose students to cutting-edge new materials and overlook the underlying scientific questions of how these new materials can be combined with 3D printing technology. High-strength hydrogels, with their solvent-rich properties and excellent biocompatibility, have extensive prospects in various fields such as tissue engineering, drug delivery, and flexible electronics. This experiment integrates the author’s recent scientific research achievements and instructs students to explore the rheological properties and swelling behavior of designated novel gel-based materials (hydrogels/organogels), effectively combining these gel-based materials with 3D printing technology, thereby gaining a more specific understanding of the processing methods of these advanced materials. The instructional design of this experiment enhances students’ in-depth understanding of Nobel Prize achievements, strengthens their awareness of applying their professional knowledge to serve national development needs, and cultivates their innovative spirit and teamwork consciousness in the face of exploration.
- 3D printing,
- Hydrogel,
- Organogel,
- Solvent replacement,
- Nobel Prize achievements
1. [1]
  Arefin, A. M. E.; Khatri, N. R.; Kulkarni,N.; Egan, P. F. Polymers 2021, 13 (9), 1499.
2. [2]
  Ngo, T. D.; Kashani, A.;Imbalzano, G.; Nguyen, K. T. Q.; Hui, D. Compos. Part B-Eng. 2018,143, 172.
3. [3]
4. [4]
5. [5]
6. [6]
  Grigoryan, B.; Paulsen,S. J.; Corbett, D. C.; Sazer, D. W.; Fortin, C. L.; Zaita, A. J.; Greenfield,P. T.; Calafat, N. J.; Gounley, J. P.; Ta, A. H. et al. Science 2019, 364 (6439), 458.
7. [7]
  Pant, A.; Lee, A. Y.;Karyappa, R.; Lee, C. P.; An, J.; Hashimoto, M.; Tan, U.; Wong, G.; Chua, C.K.; Zhang, Y. Food Hydrocolloid. 2021, 114, 106546.
8. [8]
  Zhou, Q.; Yang, K. X.;He, J. Q.; Yang, H. Y.; Zhang, X. Y. J. Mater. Chem. C 2019,7 (47), 14913.
9. [9]
  Ma, C. X.; Li, T. F.; Zhao,Q.; Yang, X. X.; Wu, J. J.; Luo, Y. W.; Xie, T. Adv. Mater. 2014,26 (32), 5665.
10. [10]
  Ma, C. X.; Lu, W.; Yang,X. X.; He, J.; Le, X. X.; Wang, L.; Zhang, J. W.; Serpe, M. J.; Huang, Y. J.;Chen, T. Adv. Funct. Mater. 2018, 28 (7), 1704568.
11. [11]
  Han, L.; Lu, X.; Wang,M. H.; Gan, D. L.; Deng, W. L.; Wang, K. F.; Fang, L. M.; Liu, K. Z.; Chan, C.W.; Tang, Y. H.; et al. Small 2017, 13 (2),1601916.
12. [12]
  Han, L.; Yan, L. W.;Wang, M. H.; Wang, K. F.; Fang, L. M.; Zhou, J.; Fang, J.; Ren, F. Z.; Lu, X. Chem.Mater. 2018, 30 (16), 5561.
13. [13]
  Xu, B.; Li, Y. M.; Gao,F.; Zhai, X. Y.; Sun, M. G.; Lu, W.; Cao, Z.; Liu, W. G. ACS Appl. Mater.Interfaces 2015, 7 (30), 16865.
14. [14]
  Ghobril, C.; Grinstaff,M. W. Chem. Soc. Rev. 2015, 44 (7), 1820.
15. [15]
  Billiet, T.;Vandenhaute, M.; Schelfhout, J.; Vlierberghe, S. V.; Dubruel, P. Biomaterials2012, 33 (26), 6020.
16. [16]
  Xing, J. F.; Zheng, M.L.; Duan, X. M. Chem. Soc. Rev. 2015, 44 (15),5031.
17. [17]
  Ambrosi, A.; Pumera, M. Chem.Soc. Rev. 2016, 45 (10), 2740.
1. [1]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
2. [2]
  Qingyang Cui , Feng Yu , Zirun Wang , Bangkun Jin , Wanqun Hu , Wan Li . From Jelly to Soft Matter: Preparation and Properties-Exploring of Different Kinds of Hydrogels. University Chemistry, 2024, 39(9): 338-348. doi: 10.3866/PKU.DXHX202309046
3. [3]
  Yuexi Guo , Zhaoyang Li , Jingwei Dai . Charlie and the 3D Printing Chocolate Factory. University Chemistry, 2024, 39(9): 235-242. doi: 10.3866/PKU.DXHX202309067
4. [4]
  Yuan Zheng , Quan Lan , Zhenggen Zha , Lingling Li , Jun Jiang , Pingping Zhu . Teaching Reform of Organic Synthesis Experiments by Introducing Reverse Thinking and Design Concepts: Taking the Synthesis of Cinnamic Acid Based on Retrosynthetic Analysis as an Example. University Chemistry, 2024, 39(6): 207-213. doi: 10.3866/PKU.DXHX202310065
5. [5]
  Xi Xu , Chaokai Zhu , Leiqing Cao , Zhuozhao Wu , Cao Guan . Experiential Education and 3D-Printed Alloys: Innovative Exploration and Student Development. University Chemistry, 2024, 39(2): 347-357. doi: 10.3866/PKU.DXHX202308039
6. [6]
  Jiajia Li , Xiangyu Zhang , Zhihan Yuan , Zhengyang Qian , Jian Zhu . 3D Printing Based on Photo-Induced Reversible Addition-Fragmentation Chain Transfer Polymerization. University Chemistry, 2024, 39(5): 11-19. doi: 10.3866/PKU.DXHX202309073
7. [7]
  Pingping Zhu , Yongjun Xie , Yuanping Yi , Yu Huang , Qiang Zhou , Shiyan Xiao , Haiyang Yang , Pingsheng He . Excavation and Extraction of Ideological and Political Elements for the Virtual Simulation Experiments at Molecular Level: Taking the Project “the Simulation and Computation of Conformation, Morphology and Dimensions of Polymer Chains” as an Example. University Chemistry, 2024, 39(2): 83-88. doi: 10.3866/PKU.DXHX202309063
8. [8]
  Chengcheng Si , Linshan Chai , Huiyuan Liu , Liye Sun , Shijian Cheng , Hailing Li , Wenyun Wang , Fang Liu , Qing Feng , Min Liu . Harry Potter China Tour Themed Innovative Science Popularization Experiment: Chemistry Magic Meets the Real World at Wuhan Station. University Chemistry, 2024, 39(9): 283-287. doi: 10.12461/PKU.DXHX202401069
9. [9]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
10. [10]
  Zhaoyang Li , Haiyan Zhao , Yali Zhang , Yuan Zhang , Shiqiang Cui . Integration of Nobel Prize Achievements in Analytical Technology with College Instrumental Analysis Course. University Chemistry, 2025, 40(3): 269-276. doi: 10.12461/PKU.DXHX202405131
11. [11]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
12. [12]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008
13. [13]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
14. [14]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
15. [15]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
16. [16]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
17. [17]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
18. [18]
  Dong-Bing Cheng , Junxin Duan , Haiyu Gao . Experimental Teaching Design on Chitosan Extraction and Preparation of Antibacterial Gel. University Chemistry, 2024, 39(2): 330-339. doi: 10.3866/PKU.DXHX202308053
19. [19]
  Haoxiang Zhang , Zhihan Zhao , Yongchen Jin , Zhiqiang Niu , Jinlei Tian . Synthesis of an Efficient Absorbent Gel: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(11): 251-258. doi: 10.12461/PKU.DXHX202401084
20. [20]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(329)
HTML views(40)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142