Citation:
Rui Gao, Ying Zhou, Yifan Hu, Siyuan Chen, Shouhong Xu, Qianfu Luo, Wenqing Zhang. Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes[J]. University Chemistry,
;2024, 39(5): 125-133.
doi:
10.3866/PKU.DXHX202310050
-
In this paper, the experimental design of undergraduate teaching was conducted based on the hot research fields of molecular switches and aggregation-induced luminescence. Photochromic diarylethene was skillfully integrated into a tetraarylethene system with aggregation-induced luminescence performance, and a new type of photoswitchable fluorescent molecular switch with both color-changing and luminescence functions was prepared. By integrating science and education, the scientific research frontier was introduced into undergraduate experimental teaching. A comprehensive experimental exploration was carried out from the aspects of material preparation, separation and purification, structure characterization and performance test. The molecular design of this experiment is concise and novel, the content is rich, and the phenomenon is obvious. On the basis of comprehensively applying and consolidating the basic theories and basic operations of undergraduate learning, this work can stimulate students’ interest in scientific research and cultivate the scientific spirit of unity and cooperation, breakthrough and innovation.
-
-
-
[1]
Irie, M. Chem. Rev. 2000, 100(5), 1685.
-
[2]
-
[3]
Zhang, J. J.; Zou, Q.; Tian, H. Adv. Mater. 2013, 25(3), 378.
-
[4]
Irie, M.; Fukaminato, T.; Matsuda, K.; Komatke, S. Chem. Rev. 2014, 114(24), 12174.
-
[5]
-
[6]
Luo, Q. F.; Cao, F.; Xiong, C. C.; Dou, Q. Y.; Qu, D. H. J. Org. Chem. 2017, 82(20), 10960.
-
[7]
Zhao, Z.; Zhang, H.; Lam, J. W. Y.; Tang, B. Z. Angew. Chem. Int. Ed. 2020, 59 (25), 9888.
-
[8]
-
[9]
Haase, F.; Lotsch, B. V. Chem. Soc. Rev. 2020, 49 (23), 8469.
-
[10]
Mei, J.; Leung, N. L.; Kwok, R. T.; Lam, J. W.; Tang, B. Z. Chem. Rev. 2015, 115 (21), 11718.
-
[11]
Zhang, J. J.; Zou, Q.; Tian, H. Adv. Mater. 2013, 25(3), 378.
-
[12]
Irie, M.; Fukaminato, T.; Matsuda, K.; Komatke, S. Chem. Rev. 2014, 114(24), 12174.
-
[13]
Natali, M.; Giordani, S. Chem. Soc. Rev. 2012, 41, 4010.
-
[14]
Ko, C. C.; Zhu, N. Y. Acc. Chem. Res. 2018, 51, 149.
-
[15]
Anderson, W. A.; Banerjee, U.; Drennan, C. L.; Elgin, S. C. R.; Epstein, I. R.; Handelsman, J.; Hatfull, G. F.; Losick, R.; O’Dowd, D. K.; Olivera, B. M.; et al. Science 2011, 331(6014), 152.
-
[16]
Lopatto, D. CBE-Life.Sci. Educ. 2007, 6(4), 297.
-
[17]
Russell, S. H.; Hancock, M. P.; McCullough, J. Science 2007, 316(5824), 548.
-
[18]
Tausch, M. W.; Meuter, N.; Spinnen, S. Educ. Quím. 2017, 28, 120.
-
[1]
-
-
-
[1]
Zishuo Yi , Peng Liu , Yan Xu . Fluorescent “Chameleon”: A Popular Science Experiment Based on Dynamic Luminescence. University Chemistry, 2024, 39(9): 304-310. doi: 10.12461/PKU.DXHX202311079
-
[2]
Yanyang Li , Zongpei Zhang , Kai Li , Shuangquan Zang . Ideological and Political Design for the Comprehensive Experiment of the Synthesis and Aggregation-Induced Emission (AIE) Performance Study of Salicylaldehyde Schiff-Base. University Chemistry, 2024, 39(2): 105-109. doi: 10.3866/PKU.DXHX202307020
-
[3]
Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050
-
[4]
Chun-Lin Sun , Yaole Jiang , Yu Chen , Rongjing Guo , Yongwen Shen , Xinping Hui , Baoxin Zhang , Xiaobo Pan . Construction, Performance Testing, and Practical Applications of a Home-Made Open Fluorescence Spectrometer. University Chemistry, 2024, 39(5): 287-295. doi: 10.3866/PKU.DXHX202311096
-
[5]
Hongxia Yan , Weixu Feng , Junyan Yao , Wei Tian , Rui Wang . Illuminating the Teaching of Science and Engineering Graduate Courses with “Curriculum Ideology and Politics”. University Chemistry, 2024, 39(6): 122-127. doi: 10.3866/PKU.DXHX202310059
-
[6]
Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, 2024, 39(10): 337-343. doi: 10.12461/PKU.DXHX202405112
-
[7]
Huirong LIU , Hao XU , Dunru ZHU , Junyong ZHANG , Chunhua GONG , Jingli XIE . Syntheses, structures, photochromic and photocatalytic properties of two viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1368-1376. doi: 10.11862/CJIC.20240066
-
[8]
Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
-
[9]
Haiyang Jin , Yonghai Hui , Yongfei Zhang , Lijun Gao , Yun Wang . Application and Exploration of Nuclear Magnetic Resonance Spectrometer in Undergraduate Basic Laboratory Teaching. University Chemistry, 2025, 40(3): 245-250. doi: 10.12461/PKU.DXHX202406022
-
[10]
Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
-
[11]
Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
-
[12]
Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
-
[13]
Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
-
[14]
Tao Cao , Fang Fang , Nianguang Li , Yinan Zhang , Qichen Zhan . Green Synthesis of p-Hydroxybenzonitrile Catalyzed by Spinach Extracts under Red-Light Irradiation: Research and Exploration of Innovative Experiments for Pharmacy Undergraduates. University Chemistry, 2024, 39(5): 63-69. doi: 10.3866/PKU.DXHX202309098
-
[15]
Tongyu Zheng , Teng Li , Xiaoyu Han , Yupei Chai , Kexin Zhao , Quan Liu , Xiaohui Ji . A DIY pH Detection Agent Using Persimmon Extract for Acid-Base Discoloration Popularization Experiment. University Chemistry, 2024, 39(5): 27-36. doi: 10.3866/PKU.DXHX202309107
-
[16]
Yuanyi Lu , Jun Zhao , Hongshuang Li . Silver-Catalyzed Ring-Opening Minisci Reaction: Developing a Teaching Experiment Suitable for Undergraduates. University Chemistry, 2024, 39(11): 225-231. doi: 10.3866/PKU.DXHX202401088
-
[17]
Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
-
[18]
Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
-
[19]
Xintian Xie , Sicong Ma , Yefei Li , Cheng Shang , Zhipan Liu . Application of Machine Learning Potential-based Theoretical Simulations in Undergraduate Teaching Laboratory Course Design. University Chemistry, 2025, 40(3): 140-147. doi: 10.12461/PKU.DXHX202405164
-
[20]
Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na3CrF6 phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
-
[1]
Metrics
- PDF Downloads(3)
- Abstract views(201)
- HTML views(33)