Citation: Jianfeng Yan, Yating Xiao, Xin Zuo, Caixia Lin, Yaofeng Yuan. Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives[J]. University Chemistry, ;2024, 39(4): 329-337. doi: 10.3866/PKU.DXHX202310005 shu

Comprehensive Chemistry Experimental Design of Ferrocenylphenyl Derivatives

College of Chemistry, Fuzhou University, Fuzhou 350108, China

Corresponding author: Yaofeng Yuan, yaofeng_yuan@fzu.edu.cn
Received Date: 9 October 2023
Revised Date: 28 November 2023

This article presents a comprehensive chemistry experiment that involves the synthesis, photophysical and electrochemical characterization of ferrocenylphenyl derivatives. By integrating multiple characterization methods and test approaches, this experiment helps students learn fundamental college chemistry theory, basic laboratory skills, and academic research in the field of organometallics. UV-Visible spectroscopic and electrochemical methods were utilized to study the target compounds and compare the electron-donating and electron-withdrawing effects on the molecular spectrum via a quantitative computation methodology. Furthermore, it stimulates the creation of green chemistry values and sustainable development mindfulness while developing students’ scientific research and comprehensive experimental skills.
- Ferrocenylphenyl derivatives,
- Aqueous synthesis,
- Photophysical,
- Electrochemistry,
- Quantum chemical calculation,
- Comprehensive chemistry experiment
1. [1]
2. [2]
3. [3]
4. [4]
  Yan, J.-F.; Men, R.-X.; Chen, X.-X.; Lin, C.-X.; Nockemann, P.; Yuan, Y.-F. New J. Chem. 2021, 45 (42), 19917.
5. [5]
6. [6]
  Tobisu, M.; Takahira, T.; Ohtsuki, A.; Chatani, N. Org. Lett. 2015, 17 (3), 680.
7. [7]
  Heijnen, D.;Tosi, F.; Vila, C.; Stuart, M. C. A.; Elsinga, P. H.; Szymanski, W.; Feringa, B. L. Angew Chem. Int. Ed. 2017, 56 (12), 3354.
8. [8]
  Carter, C.; Kratish, Y.; Jurca, T.; Gao, Y.; Marks, T. J. J. Am. Chem. Soc. 2020, 142 (43), 18715.
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
  Yamaguchi, Y.; Ding, W.; Sanderson, C. T.; Borden, M. L.; Morgan, M. J.; Kutal, C. Coord. Chem. Rev. 2007, 251 (3), 515.
15. [15]
  Nagy, A. G.; Toma, S. J. Organomet. Chem. 1984, 266 (3), 257.
16. [16]
  Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Petersson, G. A.; Nakatsuji, H.; et al. Gaussian 16, Rev. C.01; Gaussian, Inc.: Wallingford, CT, USA, 2016.
17. [17]
  Lee, C.; Yang, W.; Parr, R. G. Phys. Rev. B 1988, 37 (2), 785.
18. [18]
  Stephens, P. J.; Devlin, F. J.; Chabalowski, C. F.; Frisch, M. J. J. Phys. Chem. 1994, 98 (45), 11623.
19. [19]
  Dolg, M.; Wedig, U.; Stoll, H.; Preuss, H. J. Chem. Phys. 1987, 86 (2), 866.
20. [20]
  Dennington, R.; Keith, T. A.; Millam, J. M. GaussView, Version 6.0.16.; Semichem Inc.: Shawnee Mission, KS, USA, 2016.
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