利用双金属接力催化策略合成环状有机化合物研究进展

引用本文: 许珈铭, 向羽, 林维晟, 苗志伟. 利用双金属接力催化策略合成环状有机化合物研究进展[J]. 大学化学, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093 shu

Citation: Jiaming Xu, Yu Xiang, Weisheng Lin, Zhiwei Miao. Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies[J]. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093 shu

利用双金属接力催化策略合成环状有机化合物研究进展

许珈铭 ^1, ,
向羽 ^1, ,
林维晟 ^2, ,
苗志伟 ^{1,
,}

1.
南开大学化学学院, 元素有机化学国家重点实验室, 天津 300071;
2.
武夷学院生态与资源工程学院, 福建武夷山 354300

通讯作者: 苗志伟,Email:miaozhiwei@nankai.edu.cn

基金项目:
国家自然科学基金面上项目(22071113)；福建省南平市科技项目(N2020Z008)

摘要: 环状有机化合物在有机化学、药物化学和材料科学领域具有广泛应用，过渡金属催化的成环反应是制备多种环状化合物的有效方法之一。近年来科学家在研究单一过渡金属催化成环反应体系的基础上，进一步开发了金属/金属组合的接力催化体系，双金属接力催化体系因其可以促进单一金属催化体系无法实现的转化而受到了极大的关注。本文综述了近五年来利用双金属接力催化策略实现环状有机化合物合成的研究进展，并对该领域的发展前景进行了展望。

关键词:

English

Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies

1.
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China;
2.
Department of Ecological and Resources Engineering, Wuyi University, Wuyishan 354300, Fujian Province, China

Corresponding author: Zhiwei Miao, miaozhiwei@nankai.edu.cn

Received Date: 25 September 2023

Abstract: Cyclic organic compounds play a crucial role in organic chemistry, pharmaceutical chemistry, and materials science. Among the various methods for constructing these compounds, metal-catalyzed cycloaddition and cyclization reactions stand out as powerful approaches. In recent years, scientists have made significant advancements by developing bimetallic relay catalytic systems based on the study of single-transition-metal catalytic cyclization reactions. These bimetallic relay catalytic systems have garnered immense attention due to their ability to facilitate transformations that are unattainable through individual catalytic systems alone. This paper provides a comprehensive review of the recent progress made in the synthesis of cyclic compounds through bimetallic relay catalysis over the past five years, while also offering insights into the future directions of this exciting field.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

利用双金属接力催化策略合成环状有机化合物研究进展

通讯作者: 苗志伟,Email:miaozhiwei@nankai.edu.cn

English

Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies

Corresponding author: Zhiwei Miao, miaozhiwei@nankai.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

利用双金属接力催化策略合成环状有机化合物研究进展

通讯作者: 苗志伟,Email:miaozhiwei@nankai.edu.cn

English

Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies

Corresponding author: Zhiwei Miao, miaozhiwei@nankai.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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