过渡金属催化卤代芳烃合成苯胺类化合物的研究进展

引用本文: 宋戈洋, 薛东, 李刚. 过渡金属催化卤代芳烃合成苯胺类化合物的研究进展[J]. 大学化学, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030 shu

Citation: Geyang Song, Dong Xue, Gang Li. Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides[J]. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030 shu

过渡金属催化卤代芳烃合成苯胺类化合物的研究进展

宋戈洋 ^1,2, ,
薛东 ^1,2, ,
李刚 ^{1,2,
,}

1.
应用表面与胶体化学教育部重点实验室, 西安 710119;
2.
陕西师范大学化学化工学院, 西安 710119

通讯作者: 李刚,Email:gangli@snnu.edu.cn

基金项目:
陕西省自然科学基金面上项目(2023-JC-YB-100)；中国博士后科学基金资助项目(2023M732165)

摘要: 苯胺类化合物是一种重要的有机中间体和基本化工原料，广泛应用于医药、农药、染料和功能材料等研究领域。发展高效、绿色的合成苯胺类化合物一直是备受关注的研究热点之一。过去数十年，过渡金属催化卤代芳烃合成苯胺类化合物的研究由于具有底物适用广泛、官能团兼容性好及高的反应选择性等优点，引起了化学家的研究兴趣与关注。本文综述了过渡金属催化卤代芳烃合成苯胺类化合物的研究进展，主要内容包括：(1) 钯催化卤代芳烃合成苯胺类化合物；(2) 铜催化卤代芳烃合成苯胺类化合物；(3) 镍催化卤代芳烃合成苯胺类化合物。

关键词:

English

Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides

1.
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, Xi'an 710119, China;
2.
School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi'an 710119, China

Corresponding author: Gang Li, gangli@snnu.edu.cn

Received Date: 07 August 2023

Abstract: Aniline compounds are important organic intermediates and basic chemical raw materials, widely applied in research fields such as pharmaceuticals, agrochemicals, dyes, and functional materials. The development of efficient and versatile synthesis of aniline derivatives is one of the research hotspots that have been attracting much attention. In the past few decades, the study of transition metal-catalyzed synthesis of aniline derivatives from aryl halides has attracted significant attention from chemists due to its advantages of broad substrate applicability, good functional group compatibility, and high reaction selectivity. This review summarizes the research progress in transition metal-catalyzed synthesis of aniline derivatives from aryl halides, including: (1) palladium-catalyzed synthesis of aniline derivatives from aryl halides; (2) copper-catalyzed synthesis of aniline derivatives from aryl halides; (3) nickel-catalyzed synthesis of aniline derivatives from aryl halides.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

过渡金属催化卤代芳烃合成苯胺类化合物的研究进展

通讯作者: 李刚,Email:gangli@snnu.edu.cn

English

Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides

Corresponding author: Gang Li, gangli@snnu.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

过渡金属催化卤代芳烃合成苯胺类化合物的研究进展

通讯作者: 李刚,Email:gangli@snnu.edu.cn

English

Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides

Corresponding author: Gang Li, gangli@snnu.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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