Citation: Hai-Ying Jiang, Yueru Mu, Yuanyuan Zhang, Xue Sun, Yunxia Wang, Huilin Guo, Kefen Yue. Structure-Property-Effect Relationship of New Copper Phenylacetylene-Based Functional Materials[J]. University Chemistry, ;2023, 38(11): 206-215. doi: 10.3866/PKU.DXHX202304055 shu

Structure-Property-Effect Relationship of New Copper Phenylacetylene-Based Functional Materials

College of Chemistry and Materials Science, Northwest University, Xi'an 710127, China

Corresponding author: Hai-Ying Jiang, jianghy@nwu.edu.cn
Received Date: 18 April 2023

To develop the ability of undergraduates to analyze and solve problems using the knowledge they have acquired, this study designs a comprehensive experiment to study the structure-property-effect relationship of newly reported copper phenylacetylene (Ph-C≡C-Cu)-based functional materials. This experiment was designed based on the latest research results by thoroughly examining the basic chemistry knowledge of undergraduate students. In this experiment, different functional group modified Ph-C≡C-Cu materials were prepared, and their structures and physicochemical properties were characterized. Subsequently, their adsorption and photocatalytic degradation activities of methyl orange (MO) were studied. As a basic teaching experiment for undergraduates, this comprehensive experiment examined students' understanding, mastery, and application of the electronic effects of different functional groups in organic chemistry, liquid-solid interface interactions, solid adsorption in solution, catalytic reaction kinetics, and the determination of reaction orders in physical chemistry. Further summarizing and discussing the structure-property-effect relationship of new Ph-C≡C-Cu-based functional materials can encourage and guide undergraduates to design the structures of the target functional materials with specific properties and practical applications based on their knowledge and theories they have mastered, which will cultivate their reverse thinking mode and improve their ability to combine theory and practice.
- New functional materials,
- Copper phenylacetylene,
- Structure-property-effect relationship,
- Reverse thinking mode
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
  Sagadevan, A.; Ragupathi, A.; Lin, C.-C.; Hwu, J. R.; Hwang, K. C. Green Chem. 2015, 17, 1113.
6. [6]
  Beniazza, R.; Lambert, R.; Harmand, L.; Molton, F.; Duboc, C.; Denisov, S.; Jonusauskas, G.; McClenaghan, N. D.; Lastécouères, D.; Vincent, J.-M. Chem. Eur. J. 2014, 20 (41), 13181.
7. [7]
  Oishi, T.; Yamaguchi, K.; Mizuno, N. ACS Catal. 2011, 1, 1351.
8. [8]
  Feng, N.; Gao, C.; Guo, C.-Y.; Chen, G. ACS Appl. Mater. Interfaces 2018, 10, 5603.
9. [9]
  Liang, Q.; Chang, X.; Su, Y.; Mugo, S. M.; Zhang, Q. Angew. Chem. Int. Ed. 2021, 60, 18014.
10. [10]
  Jiang, H.-Y.; Zhou, P.; Wang, Y.; Duan, R.; Chen, C.; Song, W.; Zhao, J. Adv. Mater. 2016, 28 (41), 9776.
11. [11]
  Qian, J.; Dang, W.; Li, J.; Zhang, W.; Tian, M.; Wang, N.; Song, W.; Lv, L.; Jiang, H.-Y. Catal. Sci. Technol. 2021, 11, 2379.
12. [12]
13. [13]
  Garbusova, I. A.; Alexanjan, V. T.; Leites, L. A.; Golding, I. R.; Sladkov, A. M. J. Organometal. Chem. 1973, 54, 341.
14. [14]
15. [15]
1. [1]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
2. [2]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
3. [3]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
4. [4]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047
5. [5]
  . . Chinese Journal of Inorganic Chemistry, 2024, 40(11): 0-0.
6. [6]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
7. [7]
  Xinxue Li . The Application of Reverse Thinking in Teaching of Boiling Point Elevation and Freezing Point Depression of Dilute Solutions in General Chemistry. University Chemistry, 2024, 39(11): 359-364. doi: 10.3866/PKU.DXHX202401075
8. [8]
  Tianqi Bai , Kun Huang , Fachen Liu , Ruochen Shi , Wencai Ren , Songfeng Pei , Peng Gao , Zhongfan Liu . 石墨烯厚膜热扩散系数与微观结构的关系. Acta Physico-Chimica Sinica, 2025, 41(3): 2404024-. doi: 10.3866/PKU.WHXB202404024
9. [9]
  Yuan Zheng , Quan Lan , Zhenggen Zha , Lingling Li , Jun Jiang , Pingping Zhu . Teaching Reform of Organic Synthesis Experiments by Introducing Reverse Thinking and Design Concepts: Taking the Synthesis of Cinnamic Acid Based on Retrosynthetic Analysis as an Example. University Chemistry, 2024, 39(6): 207-213. doi: 10.3866/PKU.DXHX202310065
10. [10]
  Zitong Chen , Zipei Su , Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, 2024, 39(8): 149-162. doi: 10.3866/PKU.DXHX202311054
11. [11]
  Wenjie SHI , Fan LU , Mengwei CHEN , Jin WANG , Yingfeng HAN . Synthesis and host-guest properties of imidazolium-functionalized zirconium metal-organic cage. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 105-113. doi: 10.11862/CJIC.20240360
12. [12]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
13. [13]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
14. [14]
  Nana Wang , Gaosheng Zhang , Huosheng Li , Tangfu Xiao . Discussion on the Teaching Reform of Environmental Functional Materials within the Context of “Double First-Class” Initiative: Emphasizing the Integration of Industry, Academia, Research, and Application. University Chemistry, 2024, 39(6): 137-144. doi: 10.3866/PKU.DXHX202312010
15. [15]
  Cunming Yu , Dongliang Tian , Jing Chen , Qinglin Yang , Kesong Liu , Lei Jiang . Chemistry “101 Program” Synthetic Chemistry Experiment Course Construction: Synthesis and Properties of Bioinspired Superhydrophobic Functional Materials. University Chemistry, 2024, 39(10): 101-106. doi: 10.12461/PKU.DXHX202408008
16. [16]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
17. [17]
  Wenhao Chen , Muxuan Wu , Han Chen , Lue Mo , Yirong Zhu . Cu₂Se@C thin film with three-dimensional braided structure as a cathode material for enhanced Cu²⁺ storage. Chinese Chemical Letters, 2024, 35(5): 108698-. doi: 10.1016/j.cclet.2023.108698
18. [18]
  Jinpeng Du , Junlin Chen , Yulong Shan , Tongliang Zhang , Yu Sun , Zhongqi Liu , Xiaoyan Shi , Wenpo Shan , Yunbo Yu , Hong He . Insight into the effects of C₃H₆ on fresh and hydrothermally aged Cu-SSZ-39 catalysts. Chinese Chemical Letters, 2025, 36(3): 110019-. doi: 10.1016/j.cclet.2024.110019
19. [19]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
20. [20]
  Kaihui Huang , Boning Feng , Xinghua Wen , Lei Hao , Difa Xu , Guijie Liang , Rongchen Shen , Xin Li . Effective photocatalytic hydrogen evolution by Ti3C2-modified CdS synergized with N-doped C-coated Cu2O in S-scheme heterojunctions. Chinese Journal of Structural Chemistry, 2023, 42(12): 100204-100204. doi: 10.1016/j.cjsc.2023.100204

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(512)
HTML views(85)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142