Citation: Weiqing Zhang, Guping Hu. Comparison of Common Classical Analytical Models for Mesoporous Adsorption[J]. University Chemistry, ;2023, 38(9): 105-113. doi: 10.3866/PKU.DXHX202212053 shu

Comparison of Common Classical Analytical Models for Mesoporous Adsorption

Weiqing Zhang ,
Guping Hu ^,

School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China

Corresponding author: Guping Hu, huguping@mail.sysu.edu.cn
Received Date: 18 December 2022

The scientific characterization of the properties of mesoporous materials is a key link for their development and application. In this paper, the development history, application scope, and characteristics of mesoporous adsorption and commonly used classical analytical models are briefly introduced by tabular comparison. To systematically understand the classical mesoporous analysis methods in physical adsorption, they were classified into four categories: modeled, model-free, completely model-free, and reverse methods. Then, these methods and three frequently-used analytical software for mesoporous adsorption were compared and analyzed. This has reference value for technicians of adsorption instrument management as well as for teaching and research of mesoporous materials.
- Mesoporous material,
- Mesoporous adsorption,
- Adsorption model,
- Analytical method
1. [1]
  Brunauer, S.; Emmett, P. H.; Teller, E. J. Am. Chem. Soc. 1938, 60 (2), 309.
2. [2]
3. [3]
  Brunauer, S.; Mikhail, R. S.; Bodor, E. E. J. Colloid Interface Sci. 1967, 24 (4), 451.
4. [4]
  Shull, C. G. J. Am. chem. Soc. 1948, 70, 1405.
5. [5]
6. [6]
  Cranston, R. Adv. Catal. 1957, 9, 143.
7. [7]
  Barrett, E. P.; Joyner, L. G.; Halenda, P. P. J. Am. Chem. Soc. 1951, 73, 373.
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
  Thomson, W. Phil. Mag. 1871, 42, 448.
14. [14]
  Zsigmondy, A. Z. Anorg. Chem. 1911, 71, 356.
15. [15]
  Foster, A. G. Faraday Soc. 1932, 28, 645.
16. [16]
  Harkins, W. D.; Jura, G. J. Am. Chem. Soc. 1944, 66 (8), 1366.
17. [17]
  Wheeler, A. Adv. Catal. 1951, 3, 249.
18. [18]
  Pierce, C. J. Phys. Chem. 1953, 57 (2), 149.
19. [19]
  Montarnal, R. J. Phys. et Rad. 1953, 12, 732.
20. [20]
  Rouquerol, F.; Rouquerol, J.; Sing, K. S. W.; Llewellyn, P.; Maurin, G. Adsorption by Powders and Porous Solids, 2nd ed.; Elsevier-Academic Press:Amsterdam, The Netherlands, 2014.
21. [21]
  Innes, W. B. Anal. Chem. 1957, 29 (7), 1069.
22. [22]
  Lippens, B. C.; de Boer, J. H. J. Catal. 1964, 3, 44.
23. [23]
  Lippens, B. C.; de Boer, J. H. J. Catal. 1965, 4, 319.
24. [24]
  de Boer, J. H.; Lippens, B. C.; Linsen, B. G.; Broekhoff, J. C. P.; van den Heuvel, A.; Osinga, T. J. J. Colloid Interface Sci. 1966, 21, 405.
25. [25]
  Dollimore, D.; Heal, G. R. J. Appl. Chem. 1964, 14,109.
26. [26]
  Dollimore, D.; Heal, G. R. J. Colloid Interface Sci. 1970, 33 (4), 508.
27. [27]
  Roberts, B. F. J. Colloid Interface Sci. 1967, 23 (2), 266.
28. [28]
  Broekhoff, J. C. P.; de Boer, J. H. J. Catal. 1967, 9 (1), 15.
29. [29]
30. [30]
  Broekhoff, J. C. P.; Bodor, E. E. J. Colloid Interface Sci. 1967, 24 (4), 451.
31. [31]
  Broekhoff, J. C. P.; Bodor, E. E. J. Colloid Interface Sci. 1967, 25 (3), 353.
32. [32]
  Dollimore, D.; Heal, G. R. J. Colloid Interface Sci. 1970, 42 (2), 233.
33. [33]
34. [34]
35. [35]
36. [36]
  Kruk, M.; Jaroniec, M. Langmuir 1997, 13, 6267.
37. [37]
  Lukens, W.W.; Schmidt-Winkel, P.; Zhao, D. Y.; Feng, J. L.; Stucky, G. D. Langmuir 1999, 15, 5403.
38. [38]
  Kruk, M.; Jaroniec, M. Langmuir 1997, 13, 6267.
39. [39]
  Rocha, J. V.; Barrera, D.; Sapag, K. Top Catal. 2011, 54, 121.
40. [40]
  Rocha, J. V.; Barrera, D.; Sapag, K. Micropor. Mesopor. Mat. 2014, 200, 68.
41. [41]
  Broekhoff, J. C. P.; de Boer, J. H. J. Catal. 1968, 10 (2), 153.
42. [42]
43. [43]
  Rouquerol, J.; Llewellyn, P.; Rouquerol, F. Stud. Surf. Sci. Catal. 2007, 160, 49.
44. [44]
  Osterrieth, J.; Rampersad, J.; Madden, D.; Rampersad, N.; Storic, L.; Connolly, B.; Allendorf, M. D.; Stavila, V.; Snider, J. L; Ameloot, R.; et al. Adv. Mater. 2022, 2201502.
45. [45]
46. [46]
  Sonwane, C. G.; Bhatia, S. K. Stud. Surf. Sci. Catal. 2000, 129, 607.
47. [47]
  Groen, J. C.; Peffer, L.; Pérez-Ramírez. J. Micropor. Mesopor. Mat. 2003, 60, 1.
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