Citation:
Jie Wen, Zan Li, Jianhua Hu, Xingchen Cui, Zhina Ji, Tieqiang Wang. Preparation of Photo-thermal Responsive Soft Actuating Hydrogel Materials through Combining UV-Initiated Polymerization and In Situ Oxidation Polymerization[J]. University Chemistry,
;2023, 38(4): 98-105.
doi:
10.3866/PKU.DXHX202211090
-
Facing the lack of modernity and innovation in the current polymer science laboratory course during undergraduate education, this experiment proposes a new project for the preparation of photo-thermal responsive soft actuating hydrogel materials based on the combination of UV-initiated polymerization and in situ oxidation polymerization. The proposed experiment will first prepare thermal-responsive poly(N-isopropylacrylamide) (PNIPAM) hydrogel through UV-initiated polymerization. Then the conducting polymer with photo-thermal effect was further introduced into the PNIPAM hydrogel networks based on in situ oxidation polymerization to obtain composite hydrogel with photo-thermal responsive actuating features. Finally, the smart responsive actuating performance of the prepared composite actuating hydrogel was characterized through exposing the hydrogel under NIR irradiation. The proposed experiment focuses on the research hotspot of functional polymer materials, covering both the preparation of polymer materials based on basic polymerization methods and the characterization of functional polymer materials with specific features. The proposed experiment will not only consolidate students’ understanding of polymer polymerization methods, but also expand students’ knowledge of the research frontier of functional polymer materials. The proposed experiment possesses innovation and challenge, which is highly beneficial for improving students’ ability and quality.
-
-
-
[1]
-
[2]
Le, X. X.; Lu, W.; Zhang, J. W.; Chen, T. Adv. Sci. 2019, 6, 1801584.
-
[3]
Copaci, D.; Blanco, D.; Moreno, L. E. Actuators 2019, 8, 63.
-
[4]
Hodgins, M.; Rizzello, G.; Naso, D.; York, A.; Seelecke, S. Smart Mater. Struct. 2014, 23, 104006.
-
[5]
Merhebi, S.; Mayyas, M.; Abbasi, R.; Christoe, M. J.; Han, J.; Tang, J.; Rahim, M. A.; Yang, J.; Tan, T. T.; Chu, D.; et al. ACS Appl. Mater. Interfaces 2020, 12, 20119.
-
[6]
Deng, Z. X.; Yu, R.; Guo, B. L. Mater. Chem. Front. 2021, 5, 2092.
-
[7]
Wang, Z. W.; Zhou, H. W.; Chen, W. X.; Li, Q. Z.; Yan, B.; Jin, X. L.; Ma, A. J.; Liu, H. B.; Zhao, W. F. ACS Appl. Mater. Interfaces 2018, 10, 14045.
-
[8]
Peng, X.; Liu, T. Q.; Jiao, C.; Wu, Y. Q.; Chen, N.; Wang, H. L. J. Mater. Chem. B 2017, 5, 7997.
-
[9]
Shang, J. J.; Theato, P. Soft Matter 2018, 14, 8401.
-
[10]
Dai, C. F.; Khoruzhenko, O.; Zhang, C. Q.; Zhu, Q. L.; Jiao, D. J.; Du, M.; Breu, J.; Zhao, P.; Zheng, Q.; Wu, Z. L. Angew. Chem. Int. Ed. 2022, 61, e202207272.
-
[11]
-
[12]
Tang, L.; Wang, L.; Yang, X.; Feng, Y. Y.; Li, Y.; Feng, W. Prog. Mater. Sci. 2021, 115, 100702.
-
[1]
-
-
-
[1]
Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
-
[2]
Qingyang Cui , Feng Yu , Zirun Wang , Bangkun Jin , Wanqun Hu , Wan Li . From Jelly to Soft Matter: Preparation and Properties-Exploring of Different Kinds of Hydrogels. University Chemistry, 2024, 39(9): 338-348. doi: 10.3866/PKU.DXHX202309046
-
[3]
Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
-
[4]
Jiajia Li , Xiangyu Zhang , Zhihan Yuan , Zhengyang Qian , Jian Zhu . 3D Printing Based on Photo-Induced Reversible Addition-Fragmentation Chain Transfer Polymerization. University Chemistry, 2024, 39(5): 11-19. doi: 10.3866/PKU.DXHX202309073
-
[5]
Di WU , Ruimeng SHI , Zhaoyang WANG , Yuehua SHI , Fan YANG , Leyong ZENG . Construction of pH/photothermal dual-responsive delivery nanosystem for combination therapy of drug-resistant bladder cancer cell. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1679-1688. doi: 10.11862/CJIC.20240135
-
[6]
Wenjing ZHANG , Xiaoqing WANG , Zhipeng LIU . Recent developments of inorganic metal complex-based photothermal materials and their applications in photothermal therapy. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2356-2372. doi: 10.11862/CJIC.20240254
-
[7]
Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
-
[8]
Xiyuan Su , Zhenlin Hu , Ye Fan , Xianyuan Liu , Xianyong Lu . Change as You Want: Multi-Responsive Superhydrophobic Intelligent Actuation Material. University Chemistry, 2024, 39(5): 228-237. doi: 10.3866/PKU.DXHX202311059
-
[9]
Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
-
[10]
Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In2Se3(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
-
[11]
Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
-
[12]
Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
-
[13]
Jiahui CHEN , Tingting ZHENG , Xiuyun ZHANG , Wei LÜ . Research progress of near-infrared absorption inorganic nanomaterials in photothermal and photodynamic therapy of tumors. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2396-2414. doi: 10.11862/CJIC.20240106
-
[14]
Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
-
[15]
Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
-
[16]
Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
-
[17]
Zhuoya WANG , Le HE , Zhiquan LIN , Yingxi WANG , Ling LI . Multifunctional nanozyme Prussian blue modified copper peroxide: Synthesis and photothermal enhanced catalytic therapy of self-provided hydrogen peroxide. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2445-2454. doi: 10.11862/CJIC.20240194
-
[18]
Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304
-
[19]
Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
-
[20]
Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094
-
[1]
Metrics
- PDF Downloads(5)
- Abstract views(674)
- HTML views(89)