Citation: Nan Wang,  Qin Wang,  Hong Wang,  Fang Chen,  Min Liu,  Lihua Zhu. A Comprehensive Experiment on the Green Preparation, Characterization, and Applications of Graphene[J]. University Chemistry, ;2023, 38(9): 218-226. doi: 10.3866/PKU.DXHX202211072 shu

A Comprehensive Experiment on the Green Preparation, Characterization, and Applications of Graphene

  • Graphene exhibits excellent optical and electrical properties. Therefore, it presents remarkable potential application in “carbon neutral” technologies. We have recently developed a green mechanochemical method for preparation of edge-selectively hydroxylated graphene nanosheets using persulfate as the milling reagent. The as-prepared graphene exhibited the typical intrinsic properties of graphene and good dispersity in water. The preparation process did not require organic solvents, it involved low energy consumption, and produced little eco-friendly waste. Based on the aforementioned study, we designed an experiment on the green preparation, characterization, and applications of graphene. Various instrumental analytical methods were used to explore the structure and physicochemical properties of graphene and the applications of graphene as an energy storage material. We also compared the properties of the as-prepared graphene with those of graphene samples previously reported in the literature. This experiment should cultivate student ability to comprehensively use basic chemistry knowledge to solve real-life problems, stimulate their innovative thinking, and cultivate their “green chemistry” consciousness.
  • 加载中
    1. [1]

    2. [2]

    3. [3]

    4. [4]

    5. [5]

    6. [6]

    7. [7]

    8. [8]

    9. [9]

    10. [10]

    11. [11]

    12. [12]

      Huang, C.; Lin, J.; Tang, H.; Wang, Q.; Majima, T.; Wang, N.; Luo, Z.; Zhu, L. ChemSusChem 2022, e202201496.

    13. [13]

      Zhu, Y.; James, D. K.; Tour, J. M. Adv. Mater. 2012, 24, 4924.

    14. [14]

      Jeon, I. Y.; Shin, Y. R.; Sohn, G. J.; Choi, H. J.; Bae, S. Y.; Mahmood, J.; Jung, S. M.; Seo, J. M.; Kim, M. J.; Chang, D. W.; et al. Proc. Natl. Acad. Sci. USA 2012, 109, 5588.

    15. [15]

      Lin, T.; Chen, J.; Bi, H.; Wan, D.; Huang, F.; Xie X.; Jiang, M. J. Mater. Chem. A 2013, 1, 500.

    16. [16]

      Jeon, I.; Choi, H.; Jung, S.; Seo, J.; Kim, M.; Dai, L.; Baek, J. J. Am. Chem. Soc. 2013, 135, 1386.

    17. [17]

      Kolthoff, I. M.; Miller. I. K. J. Am. Chem. Soc. 1951, 73, 3055.

    18. [18]

      Chen, N.; Yang, R. T. J. Phys. Chem. A 1998, 102, 6348.

    19. [19]

      Huang, A.; Zhang, Z.; Wang, N.; Zhu, L.; Zou, J. J. Hazard. Mater. 2016, 302, 158.

    20. [20]

      Wang, N.; Lv, H.; Zhou, Y.; Zhu, L.; Hu, Y.; Majima, T.; Tang, H. Environ. Sci. Technol. 2019, 53, 8302.

    21. [21]

      Su, R.; Lin, S. F.; Chen, D. Q.; Chen, G. H. J. Phys. Chem. C 2014, 118, 12520.

    22. [22]

      Li, Z.; Kinloch, I. A.; Young, R. J.; Novoselov, K. S.; Anagnostopoulos, G.; Parthenios, J.; Galiotis, C.; Papagelis, K.; Lu, C.; Britnell, L. ACS Nano 2015, 9, 3917.

    23. [23]

    24. [24]

      Eckmann, A.; Felten, A.; Mishchenko, A.; Britnell, L.; Krupke, R.; Novoselov K. S.; Casiraghi, C. Nano Lett. 2012, 12, 3925.

    25. [25]

      Robinson, J. T.; Tabakman, S. M.; Liang, Y.; Wang, H.; Casalongue, H. S.; Vinh, D.; Dai, H. J. Am. Chem. Soc. 2011, 133, 6825.

  • 加载中
    1. [1]

      Lei Shu Zhengqing Hao Kai Yan Hong Wang Lihua Zhu Fang Chen Nan Wang . Development of a Double-Carbon Related Experiment: Preparation, Characterization and Carbon-Capture Ability of Eggshell-Derived CaO. University Chemistry, 2024, 39(4): 149-156. doi: 10.3866/PKU.DXHX202310134

    2. [2]

      Zijian Zhao Yanxin Shi Shicheng Li Wenhong Ruan Fang Zhu Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094

    3. [3]

      Jihua Deng Xinshi Wu Dichang Zhong . Exploration of Green Teaching and Ideological and Political Education in Chemical Experiment of “Preparation of Ammonium Ferrous Sulfate”. University Chemistry, 2024, 39(10): 325-329. doi: 10.12461/PKU.DXHX202405046

    4. [4]

      Qi Wang Yicong Gao Feng Lu Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141

    5. [5]

      Wei Shao Wanqun Zhang Pingping Zhu Wanqun Hu Qiang Zhou Weiwei Li Kaiping Yang Xisheng Wang . Design and Practice of Ideological and Political Cases in the Course of Instrument Analysis Experiment: Taking the GC-MS Experiment as an Example. University Chemistry, 2024, 39(2): 147-154. doi: 10.3866/PKU.DXHX202309048

    6. [6]

      Tingting Yu Si Chen Lianglong Sun Tongtong Shi Kai Sun Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022

    7. [7]

      Feng Han Fuxian Wan Ying Li Congcong Zhang Yuanhong Zhang Chengxia Miao . Comprehensive Organic Chemistry Experiment: Phosphotungstic Acid-Catalyzed Direct Conversion of Triphenylmethanol for the Synthesis of Oxime Ethers. University Chemistry, 2025, 40(3): 342-348. doi: 10.12461/PKU.DXHX202405181

    8. [8]

      Jingming Li Bowen Ding Nan Li Nurgul . Application of Comparative Teaching Method in Experimental Project Design of Instrumental Analysis Course: A Case Study in Chromatography Experiment Teaching. University Chemistry, 2024, 39(8): 263-269. doi: 10.3866/PKU.DXHX202312078

    9. [9]

      Wanqun Hu Pingping Zhu Yuan Zheng Wanqun Zhang Wei Shao Hong Wu Qiang Zhou Kaiping Yang Xiang Sheng . Design and Practice of Ideological and Political Case Study in Instrumental Analysis Experiment Course: the Extraction and Structural Identification of Artemisinin. University Chemistry, 2024, 39(2): 203-207. doi: 10.3866/PKU.DXHX202310062

    10. [10]

      Zunxiang Zeng Yuling Hu Yufei Hu Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO2Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069

    11. [11]

      Xia Gao Huibin Pan Chengfang Qiao Fengying Chen Jun Wang Qian Liu . Teaching Reform and Practice of Chemistry Comprehensive Experiment Course under Professional Certification Background. University Chemistry, 2024, 39(10): 195-202. doi: 10.12461/PKU.DXHX202401078

    12. [12]

      Tianlong Zhang Rongling Zhang Hongsheng Tang Yan Li Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006

    13. [13]

      Juan Yuan Bin Zhang Jinping Wu Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu2(Salen)2 Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014

    14. [14]

      Kun Xu Xinxin Song Zhilei Yin Jian Yang Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050

    15. [15]

      Yang Chen Peng Chen Yuyang Song Yuxue Jin Song Wu . Application of Chemical Transformation Driven Impurity Separation in Experiments Teaching: A Novel Method for Purification of α-Fluorinated Mandelic Acid. University Chemistry, 2024, 39(6): 253-263. doi: 10.3866/PKU.DXHX202310077

    16. [16]

      Ling Liu Haibin Wang Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080

    17. [17]

      Yinwu Su Xuanwen Zheng Jianghui Du Boda Li Tao Wang Zhiyan Huang . Green Synthesis of 1,3-Dibromoacetone Using Halogen Exchange Method: Recommending a Basic Organic Synthesis Teaching Experiment. University Chemistry, 2024, 39(5): 307-314. doi: 10.3866/PKU.DXHX202311092

    18. [18]

      Yinuo Wang Siran Wang Yilong Zhao Dazhen Xu . Selective Synthesis of Diarylmethyl Anilines and Triarylmethanes via Multicomponent Reactions: Introduce a Comprehensive Experiment of Organic Chemistry. University Chemistry, 2024, 39(8): 324-330. doi: 10.3866/PKU.DXHX202401063

    19. [19]

      Yihao Zhao Jitian Rao Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050

    20. [20]

      Xue Dong Xiaofu Sun Shuaiqiang Jia Shitao Han Dawei Zhou Ting Yao Min Wang Minghui Fang Haihong Wu Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO2制C2+产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012

Metrics
  • PDF Downloads(11)
  • Abstract views(753)
  • HTML views(56)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return