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Citation: Yaru Liu, Yurao Jia, Lan Xu, Sheng Zhang, Linbin Yao. Designing and Exploring “Visible” B←N Bond Coordination Compounds Based on Lewis Acid-Base Interaction in Laboratory Teaching[J]. University Chemistry, ;2023, 38(4): 300-310. doi: 10.3866/PKU.DXHX202210016 shu

Designing and Exploring “Visible” B←N Bond Coordination Compounds Based on Lewis Acid-Base Interaction in Laboratory Teaching

School of Science, Hainan University, Haikou 570228, China

Corresponding author: Sheng Zhang, zhangsheng19890501@163.com
Received Date: 10 October 2022

In this experiment, the electron-deficient boron and the electron-donating nitrogen were used as the starting points of the rational design. Furthermore, organic carriers of B and N were selected based on the principle of aggregation-induced emission (AIE). An environmentally friendly, economic and convenient “one-pot” synthesis method was employed to obtain crystal compounds, and the structures of these compounds were characterized. The optical properties of compounds, including “presence or absence”, “color”, and “strength”, were regulated by changing ligands. Students will understand the idea that the structure determines properties and will experience the visible and tangible chemical theories.
- Lewis acid-base theory,
- Aggregation-induced emission,
- Tenon and mortise structure,
- Boron,
- Nitrogen
1. [1]
2. [2]
3. [3]
4. [4]
  Lewis, G. N. Valence and the Structure of Atoms and Molecules; Chemical Catalogue Company:New York, NY, USA, 1923.
5. [5]
6. [6]
  Hong, Y.; Lam, J. W. Y.; Tang, B. Z. Chem. Soc. Rev. 2011, 40, 5361.
7. [7]
  Hong, Y.; Lam, J. W. Y.; Tang, B. Z. Chem. Commun. 2009, 29, 4332.
8. [8]
  Xie, Y. J.; Li, Z. Natl. Sci. Rev. 2021, 8, nwaa199.
9. [9]
  Dang, D. F.; Qiu, Z. J.; Han, T.; Liu, Y.; Chen, M.; Kwok, R. T. K.; Lam, J. W. Y.; Tang B. Z. Adv. Funct. Mater. 2018, 28, 1707210.
1. [1]
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