Citation: Jianhui Zhang, Weiqing Zhang. Comparison of Common Classical Analytical Models for Microporous Adsorption[J]. University Chemistry, ;2023, 38(8): 326-332. doi: 10.3866/PKU.DXHX202208134 shu

Comparison of Common Classical Analytical Models for Microporous Adsorption

Jianhui Zhang ,
Weiqing Zhang ^,

School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China

Corresponding author: Weiqing Zhang, ceszwq@mail.sysu.edu.cn
Received Date: 31 August 2022

This paper briefly compares the source, application scope, development history and respective characteristics of the commonly used classical models of microporous adsorption. In order to facilitate the systematic understanding and mastery of classical microporous analysis methods in physical adsorption, the methods are divided into three categories:(1) methods developed from standard isotherms, including t-method, α_s-method, n-method and MP method; (2) methods based on micropore filling theory, including D-R method, D-A method and D-R-S method; (3) the currently commonly used methods include the original HK method (slit pore), HK-SF method (cylindrical pore), HK-CY method (spherical pore) and the improved HK method.
- t-method,
- MP method,
- D-R equation,
- Original H-K equation,
- Improved H-K equation
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