Citation: Shiyu Hu, Kailing Wu, Zihao Ye, Yongmei Liu. Hydrogen Production from Formate Decomposition Catalyzed by Carbon-Supported Pd[J]. University Chemistry, ;2023, 38(8): 145-155. doi: 10.3866/PKU.DXHX202208129 shu

Hydrogen Production from Formate Decomposition Catalyzed by Carbon-Supported Pd

Shiyu Hu ¹ ,
Kailing Wu ¹ ,
Zihao Ye ¹ ,
Yongmei Liu ^1,2,,

1.
Chemistry Department, Fudan University, Shanghai 200433, China;
2.
National Demonstration Center for Experimental Chemistry Education (Fudan University), Shanghai 200433, China

Corresponding author: Yongmei Liu, ymliu@fudan.edu.cn
Received Date: 31 August 2022

Realizing high-efficiency H₂ production under practical, mild conditions is essential to meet the requirements to develop this source of ideal clean, alternative energy; thus, this attracted wide spread interest. Catalytic decomposition of formic acid-formate is one of the most widely studied options to achieve this. Herein, we demonstrate H₂ production from HCOOK over Pd/C catalysts, in which a flexible content is allowed by modulating the catalyst preparation conditions, reaction conditions, and catalytic characterizations. This experiment not only includes basic chemical kinetics but also guides students to accumulate innovative consciousness through thinking about the structure-activity relationship of catalysts by structural characterization. In addition, this experiment enriches teaching content, improves teaching efficiency, and exercises students' cooperation ability through modular design and group teaching. This project relies on the National Demonstration Center for Experimental Education to build an inter-school resource sharing platform to realize the sharing of experimental data and characterization results that colleges can then use to freely select the required information to enrich students' experiment reports.
- Palladium catalyst,
- Potassium formate decomposition to hydrogen,
- New energy development,
- Modular experimental design,
- Resource sharing
1. [1]
2. [2]
  Partridge, J. K. Adv. Cryog. Eng. 2012, 57, 1765.
3. [3]
4. [4]
  Salmelin, B. J. Prod. Innov. Manage. 2013, 1 (2), 4.
5. [5]
  Itaoka, K.; Saito, A.; Sasaki, K. Int. J. Hydrogen Energ. 2017, 42 (11), 7290.
6. [6]
7. [7]
  Dervis, E. D. Hydrogen Storage Technologies; Springer:Berlin, Heidelberg, Germany, 2017.
8. [8]
  Reutemann, W.; Kieczka, H. Formic Acid in Ullmann's Encyclopedia of Industrial Chemistry; Wiley-VCH, Weinheim, Germany, 2005.
9. [9]
  Boddien, A.; Gärtner, F.; Federsel, C.; Sponholz, P.; Mellmann, D.; Jackstell, R.; Junge, H.; Belier, M. Angew. Chem. Int. Ed. 2011, 50, 6411.
10. [10]
  Papp, G.; Csorba, J.; Laurenczy, G.; Joó, F. Angew. Chem. Int. Ed. 2011, 50, 10433.
11. [11]
  Stalder, C. J.; Chao, S.; Summers, D. P.; Wrighton, M. S. J. Am. Chem. Soc. 1983,105, 6318.
12. [12]
  Wiener, H.; Saaaon, Y.; Blum, J. J. Mol. Catal. 1986, 35, 277.
13. [13]
  Zhou, X.; Huang, Y.; Xing, W.; Liu, C.; Liao, J.; Lu, T. Chem. Commun. 2008, 30, 3540.
14. [14]
15. [15]
  Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Scalmani, G.; Barone, V.; Petersson, G. A.;Nakatsuji, H.; et al. Gaussian 16, Revision B.01; Gaussian, Inc.:Wallingford, CT, USA 2016.
16. [16]
  Zhu, Q.; Song, F.; Nobuko, T.; Yuichiro, H.; Tom, A.; Xu, Q. J. Mater. Chem. A 2018, 6, 5544.
17. [17]
  Dai, H.; Cao, N.; Yang, L.; Luo, W.; Cheng, G. J. Mater. Chem. A 2014, 2, 11060.
18. [18]
19. [19]
20. [20]
1. [1]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
2. [2]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
3. [3]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
4. [4]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
5. [5]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
6. [6]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
7. [7]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
8. [8]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
9. [9]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
10. [10]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
11. [11]
  Xi YANG , Chunxiang CHANG , Yingpeng XIE , Yang LI , Yuhui CHEN , Borao WANG , Ludong YI , Zhonghao HAN . Co-catalyst Ni₃N supported Al-doped SrTiO₃: Synthesis and application to hydrogen evolution from photocatalytic water splitting. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 440-452. doi: 10.11862/CJIC.20240371
12. [12]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
13. [13]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
14. [14]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
15. [15]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
16. [16]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
17. [17]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
18. [18]
  Xiaofeng Xia , Jielian Zhu . Innovative Comprehensive Experimental Design: Synthesis of 6-Fluoro-N-benzoyl Tetrahydroquinoline. University Chemistry, 2024, 39(10): 344-352. doi: 10.12461/PKU.DXHX202405063
19. [19]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
20. [20]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(1111)
HTML views(104)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142