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Citation: Zhiqiang Dong, Bo Yi, Yechao Chen, Xin Chen, Chanzi Ruan, Chunyan Zhang, Zhenling Xu, Rui Pan, Yinyun Lü, Yuhua Weng, Wenwei Zhang, Yanping Ren. Results and Discussion on the Solvato/Thermochromic Behavior of[Ni(Me₃en)(acac)]BPh₄ Complex: The Results and Discussion on the Part of Inorganic and Analytical Chemistry Experiment of “The 10th National Undergraduate Chemistry Laboratory Tournament”[J]. University Chemistry, ;2023, 38(8): 333-340. doi: 10.3866/PKU.DXHX202208019 shu

Results and Discussion on the Solvato/Thermochromic Behavior of[Ni(Me₃en)(acac)]BPh₄ Complex: The Results and Discussion on the Part of Inorganic and Analytical Chemistry Experiment of “The 10th National Undergraduate Chemistry Laboratory Tournament”

Zhiqiang Dong ¹ ,
Bo Yi ¹ ,
Yechao Chen ¹ ,
Xin Chen ¹ ,
Chanzi Ruan ¹ ,
Chunyan Zhang ¹ ,
Zhenling Xu ¹ ,
Rui Pan ¹ ,
Yinyun Lü ¹ ,
Yuhua Weng ¹ ,
Wenwei Zhang ^2,, ,
Yanping Ren ^1,,

1.
National Demonstration Center for Experimental Chemistry Education (Xiamen University), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, China;
2.
National Demonstration Center for Experimental Chemistry Education (Nanjing University), College of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: Wenwei Zhang, Yanping Ren,
Received Date: 2 August 2022

This paper mainly introduces the inorganic and analytical chemistry laboratory project, the synthesis of the complex[Ni(Me₃en)(acac)]BPh₄ and the solvato/thermochromic behavior, designed by Nanjing University for "The 10th National Undergraduate Chemistry Laboratory Tournament". This paper mainly deals with the experiment implementation process, results and related issues of the solvato/thermochromic behavior in the experiment. In the paper, the detailed and intuitive experimental phenomena inspire students to explore and understand the mechanism. The law of solvato/thermochromic behavior is summarized, which allows students to intuitively understand that the structure of complexes determines their properties. In the process, students can develop the ability of analysis, judgment, induction, summarizing and critical thinking.
- Ni(II) complex,
- Solvato/Thermochromic behavior and mechanism,
- Analysis and discussion of experimental results
1. [1]
2. [2]
3. [3]
4. [4]
  Fukuda, Y.; Sone, K. J. Inorg. Nucl. Chem. 1972, 34, 2315.
5. [5]
  Yusuke, F.; Tomoyuki, M. Chem. Commun. 2013, 49, 4688.
6. [6]
  Hitoshi, H.; Tomoyuki, M. Langmuir 2015, 31, 13048.
7. [7]
8. [8]
  Nguyen, T.; Yutaka, F.; Sone, K. Bull. Chem. Soc. Japan 1977,50, 154.
9. [9]
10. [10]
1. [1]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
2. [2]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
3. [3]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
4. [4]
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5. [5]
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6. [6]
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9. [9]
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12. [12]
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13. [13]
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14. [14]
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15. [15]
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16. [16]
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17. [17]
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18. [18]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
19. [19]
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20. [20]
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Results and Discussion on the Solvato/Thermochromic Behavior of[Ni(Me3en)(acac)]BPh4 Complex: The Results and Discussion on the Part of Inorganic and Analytical Chemistry Experiment of “The 10th National Undergraduate Chemistry Laboratory Tournament”

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通讯作者: 陈斌, bchen63@163.com

Results and Discussion on the Solvato/Thermochromic Behavior of[Ni(Me₃en)(acac)]BPh₄ Complex: The Results and Discussion on the Part of Inorganic and Analytical Chemistry Experiment of “The 10th National Undergraduate Chemistry Laboratory Tournament”