Citation: Tian He, Jingtao Ye, Yang Li, Shouchun Yin. Lead by “Practice and Use” with a Loud Voice: A Comprehensive Experiment of the Synthesis and Photothermal Performance of Water-Soluble Near-Infrared Organic Nanomaterials[J]. University Chemistry, ;2023, 38(5): 143-148. doi: 10.3866/PKU.DXHX202207155 shu

Lead by “Practice and Use” with a Loud Voice: A Comprehensive Experiment of the Synthesis and Photothermal Performance of Water-Soluble Near-Infrared Organic Nanomaterials

Provincial Chemical Experimental Teaching Demonstrating Center, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hanghzou 311121, China

Corresponding author: Shouchun Yin, yinsc@hznu.edu.cn
Received Date: 30 July 2022

Near-infrared (NIR) plays a vital role in the fields of photothermal therapy, bioimaging, photodynamic therapy, and medical diagnosis. In this comprehensive experiment, organic nanoparticles based on electron-transfer complexes (viz., coronene (COR) and 7,7,8,8-tetracyano-p-benzoquinonedimethane (TCNQ)) were prepared via precipitation. Absorption in the NIR regions was determined using ultraviolet-visible spectrophotometry, and the structure of the nanoparticles was analyzed using dynamic light scattering and transmission electron microscopy. The photothermal properties of the nanoparticles were evaluated via infrared thermal imaging. This study applies the frontier of scientific research to experimental teaching, which helps students to consolidate their scientific knowledge, improve their experimental skills and laboratory safety consciousness, broaden their scientific research vision, and instill the exploration spirit of scientific theoretical research with the ultimate goal of application “landing”.
- Organic nanomaterials,
- Near-infrared (NIR),
- Water-soluble,
- Photothermal,
- Comprehensive experiment
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
  Li, S.; Deng, Q.; Zhang, Y.; Li, X.; Wen, G.; Cui, X.; Wan, Y.; Huang, Y.; Chen, J.; Liu, Z.; et al. Adv. Mater. 2020, 32, 2001146.
6. [6]
  Liu, S.; Li, Y.; Kwok, R. T. K.; Lam, J. W. Y.; Tang B. Z. Chem. Sci. 2021, 12, 3427.
7. [7]
  Liang, Y.; Zhang, H.; Yuan, H.; Lu, W.; Li, Z.; Wang L.; Gao, L. H. ACS Appl. Bio Mater. 2020, 3, 3494.
8. [8]
  Li, X.; Fang, F.; Sun, B.; Yin, C.; Tan, J.; Wan, Y.; Zhang, J.; Sun, P.; Fan, Q.; Wang, P.; et al. Nanoscale Horiz. 2021, 6, 177.
9. [9]
  Jiang, Y.; Li, J.; Zhen, X.; Xie, C.; Pu, K. Adv. Mater. 2018, 30, 1705980.
10. [10]
  Li, X.; Liu, L.; Li, S.; Wan, Y.; Chen, J. X.; Tian, S.; Huang, Z.; Xiao, Y. F.; Cui, X.; Xiang, C.; et al. ACS Nano 2019, 13, 12901.
11. [11]
  Tian, S.; Bai, H. T.; Li, S. L.; Xiao, Y. F.; Cui, X.; Li, X. Z.; Tan, J. H.; Huang, Z. M.; Shen, D.; Liu, W. M.; et al. Angew. Chem. Int. Ed. 2021, 60, 11758.
12. [12]
  Lyu, Y.; Xie, C.; Chechetka, S. A.; Miyako, E.; Pu, K. J. Am. Chem. Soc. 2016, 138, 9049.
13. [13]
  He, S.; Jiang, Y.; Li, J.; Pu, K. Angew. Chem. Int. Ed. 2020, 59, 10633.
14. [14]
  Yang, K.; Xu, H.; Cheng, L.; Sun, C.; Wang, J.; Liu, Z. Adv. Mater. 2012, 24, 5586.
15. [15]
  Sheng, Z.; Hu, D.; Zheng, M.; Zhao, P.; Liu, H.; Gao, D.; Gong, P.; Gao, G.; Zhang, P.; Ma, Y.; et al. ACS Nano 2014, 8, 12310.
16. [16]
17. [17]
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