Citation: Pengwei Cheng, Zhen Luo, Yucan Che, Yuwen Liu, Fusheng Ke, Gongzhen Cheng. 过氧化铜和氧化铜的制备及其电化学还原CO₂性能研究——推荐一个综合研究型无机化学实验[J]. University Chemistry, ;2022, 37(11): 220714. doi: 10.3866/PKU.DXHX202207146 shu

过氧化铜和氧化铜的制备及其电化学还原CO₂性能研究——推荐一个综合研究型无机化学实验

College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, China

Corresponding author: Fusheng Ke, kefs@whu.edu.cn
Received Date: 30 July 2022

铜基催化剂能高效地将CO₂深度电化学还原（CO₂RR）为多碳烃类化合物，其催化性能与催化剂的结构有关。我们以大学无机化学实验“过氧化钙的制备及含量测定”为基础，设计了集合成、形貌结构表征和CO₂RR的性能应用研究为一体的综合研究型实验。结果表明铜氧化物催化剂的形貌结构对CO₂RR产物的选择性具有显著的差异。本综合研究型实验内容丰富，有助于提升学生化学专业核心素养，符合新时代化学学科的发展要求。
- Electrochemical reduction of CO₂,
- Copper peroxide,
- Copper oxide,
- Comprehensive research experiment
1. [1]
  Li, L.; Li, X.; Sun, Y.; Xie, Y. Chem. Soc. Rev. 2022, 51 (4), 1234.
2. [2]
3. [3]
  Wang, G.; Chen, J.; Ding, Y.; Cai, P.; Yi, L.; Li, Y.; Tu, C.; Hou, Y.; Wen, Z.; Dai, L. Chem. Soc. Rev. 2021, 50 (8), 4993.
4. [4]
  Overa, S.; Ko, B. H.; Zhao, Y. R.; Jiao, F. Acc. Chem. Res. 2022, 55 (5), 638.
5. [5]
  Ke, F. S.; Liu, X. C.; Wu, J.; Sharma, P. P.; Zhou, Z. Y.; Qiao, J.; Zhou, X. D. Catal. Today 2017, 288, 18.
6. [6]
  Li, C. W.; Kanan, M. W. J. Am. Chem. Soc. 2012, 134, 7231.
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
  Lin, L. S.; Huang, T.; Song, T.; Ou, X. Y.; Wang, Z.; Deng, H.; Tian, R.; Liu, Y.; Wang, J. F.; Liu, Y. J. Am. Chem. Soc. 2019, 141 (25), 9937.
13. [13]
  Jannesari, M.; Akhavan, O.; Hosseini, H. R. M.; Bakhshi, B. ACS Appl. Mater. Interfaces 2020, 12 (32), 35813.
14. [14]
  Wang, X.; Wang, Y.; Sang, X.; Zheng, W.; Zhang, S.; Shuai, L.; Yang, B.; Li, Z.; Chen, J.; Lei, L. Angew. Chem. Int. Ed. 2021, 60 (8), 4192.
15. [15]
  Kim, C.; Bui, J. C.; Luo, X.; Cooper, J. K.; Kusoglu, A.; Weber, A. Z.; Bell, A. T. Nat. Energy 2021, 6 (11), 1026.
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
1. [1]
  Zhuoya WANG , Le HE , Zhiquan LIN , Yingxi WANG , Ling LI . Multifunctional nanozyme Prussian blue modified copper peroxide: Synthesis and photothermal enhanced catalytic therapy of self-provided hydrogen peroxide. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2445-2454. doi: 10.11862/CJIC.20240194
2. [2]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
3. [3]
  Rong Tian , Yadi Yang , Naihao Lu . Comprehensive Experimental Design of Undergraduate Students Based on Interdisciplinarity: Study on the Effect of Quercetin on Chlorination Activity of Myeloperoxidase. University Chemistry, 2024, 39(8): 247-254. doi: 10.3866/PKU.DXHX202312064
4. [4]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
5. [5]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
6. [6]
  Ronghao Zhao , Yifan Liang , Mengyao Shi , Rongxiu Zhu , Dongju Zhang . Investigation into the Mechanism and Migratory Aptitude of Typical Pinacol Rearrangement Reactions: A Research-Oriented Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 305-313. doi: 10.3866/PKU.DXHX202309101
7. [7]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
8. [8]
  Qijin Mo , Meifang Zhuo , Zhiyi Zhong , Chunfang Gan , Lixia Zhang . Research-Oriented Experimental Teaching in Chemistry Education at Normal University: Taking the Project of Recovering Silver Nitrate from Silver-Containing Waste as an Example. University Chemistry, 2024, 39(6): 201-206. doi: 10.3866/PKU.DXHX202310099
9. [9]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
10. [10]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
11. [11]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
12. [12]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
13. [13]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
14. [14]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
15. [15]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
16. [16]
  Yuejiao An , Wenxuan Liu , Yanfeng Zhang , Jianjun Zhang , Zhansheng Lu . Revealing Photoinduced Charge Transfer Mechanism of SnO₂/BiOBr S-Scheme Heterostructure for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2407021-. doi: 10.3866/PKU.WHXB202407021
17. [17]
  Tingting Jiang , Jing Chang . Application of Ideological and Political Education in Chemical Analysis Experiment under the Background of Emerging Engineering Education: Taking the Redox Titration Experiment as an Example. University Chemistry, 2024, 39(2): 168-174. doi: 10.3866/PKU.DXHX202308007
18. [18]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
19. [19]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
20. [20]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(1072)
HTML views(261)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

过氧化铜和氧化铜的制备及其电化学还原CO2性能研究——推荐一个综合研究型无机化学实验

Metrics

通讯作者: 陈斌, bchen63@163.com

过氧化铜和氧化铜的制备及其电化学还原CO₂性能研究——推荐一个综合研究型无机化学实验