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Citation: Yilun Li, Xianggui Zhang, Yaofeng Yuan, Keyin Ye. Metallo-Anomeric Effect[J]. University Chemistry, ;2023, 38(5): 119-123. doi: 10.3866/PKU.DXHX202206101 shu

Metallo-Anomeric Effect

College of Chemistry, Fuzhou University, Fuzhou 350108, China

Received Date: 29 June 2022

The anomeric effect, one of the classic stereoelectronic effects in organic chemistry, describes the preference of an electronegative substituent at the anomeric carbon of glycosides to adopt the axial configuration. Herein, we briefly survey the history and broad applications of the anomeric effect in organic synthesis. Particularly, we highlight the recent investigations on the related metallo-anomeric effect in carbohydrate chemistry and the possible strategies for its easy regulation via the alteration of the metal, oxidation state, ligand, and structure of the substrate. A positive interplay between scientific research and organic chemistry teaching would profoundly help students to understand the basic concepts and advanced applications of the metallo-anomeric effect.
- Gauche effect,
- Anomeic effect,
- Stereoelectronic effect,
- Conformation
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