Citation: Heng Zhang, Jinshuai Liu, Jiadun Wei, Yan Gao, Qian Wu, Gang Liu, Ying Ma, Fen Wang, Chunjiang Jia, Shiling Yuan. Analysis of Alcoholic Beverage Residues in Archaeological Sherd[J]. University Chemistry, ;2023, 38(2): 207-213. doi: 10.3866/PKU.DXHX202206025 shu

Analysis of Alcoholic Beverage Residues in Archaeological Sherd

Heng Zhang ¹ ,
Jinshuai Liu ¹ ,
Jiadun Wei ¹ ,
Yan Gao ² ,
Qian Wu ² ,
Gang Liu ¹ ,
Ying Ma ¹ ,
Fen Wang ² ,
Chunjiang Jia ¹ ,
Shiling Yuan ^1,,

1.
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China;
2.
School of History and Culture, Shandong University, Jinan 250100, China

Corresponding author: Shiling Yuan, shilingyuan@sdu.edu.cn
Received Date: 9 June 2022

This experiment introduces the application of chemistry in archaeology through the detection and analysis of alcoholic beverage residues in pottery. Organic acids which are the indicators of alcoholic beverage residues are extracted through a series of experimental steps such as extraction, filtration, centrifugation and rotary evaporation, and measured by High Performance Liquid Chromatography (HPLC). Combined with archaeological background of pottery, the results of this experiment can be used to analyze the possible usage of the pottery. Based on emerging interdisciplinary archaeological chemistry, this experiment is offered to students majoring in chemistry and archaeology, which could provide insights into fundamental concepts, basic methods of sample isolation and HPLC analysis, as well as provide primary perception of the focused topic in archaeology.
- Archaeological chemistry,
- Alcoholic beverage residues,
- Organic acid,
- HPLC
1. [1]
2. [2]
3. [3]
  Michel, R. H.; McGovern, P. E.; Badler, V. R. Anal. Chem. 1993, 65 (8), 408.
4. [4]
  Romanus, K.; Baeten, J.; Poblome, J.; Accardo, S.; Degryse, P.; Jacobs, P.; Vos, D. D.; Waelkens, M. J. Archaeol. Sci. 2009, 36 (3), 900.
5. [5]
  Barnard, H.; Dooley, A. N.; Areshian, G.; Areshian, G.; Gasparyan, B.; Faull, K. F. J. Archaeol. Sci. 2011, 38 (5), 977.
6. [6]
  McGovern, P. E.; Jalabadze, M.; Batiuk, S.; Callahan, M. P.; Smith, K. E.; Hall, G. R.; Kvavadze, E.; Maghradze, D.; Rusishvili, N.; Bouby, L.; et al. Proc. Natl. Acad. Sci. U. S. A. 2017, 114 (48), 10309.
7. [7]
8. [8]
  McGovern, P. E.; Hartung, U.; Badler, V. R.; Glusker, D. L.; Exner, L. J. Expedition 1997, 39 (1), 3.
9. [9]
  Guasch-Jane, M. R.; Ibern-Gomez, M.; Andres-Lacueva, C.; Jauregui, O.; Lamuela-Raventos, R. M. Anal. Chem. 2004, 76 (6), 1672.
10. [10]
  McGovern, P. E.; Zhang, J.; Tang, J.; Zhang, Z.; Hall, G. R.; Moreau, R. A.; Nunez, A.; Butrym, E. D.; Richards, M. P.; Wang, C.; et al. Proc. Natl. Acad. Sci. U. S. A. 2004, 101 (51), 17593.
11. [11]
  McGovern, P. E.; Mirzoian, A.; Hall, G. R. Proc. Natl. Acad. Sci. U. S. A. 2009, 106 (18), 7361.
12. [12]
  Pecci, A.; Giorgi, G.; Salvini, L.; Ontiveros, M. A. C. J. Archaeol. Sci. 2013, 40 (1), 109.
13. [13]
  Pecci, A.; Ontiveros, M. Á. C.; Garnier, N. J. Archaeol. Sci. 2013, 40 (12), 4491.
14. [14]
  Teodor, E. D.; Badea, G. I.; Alecu, A.; Calu, L.; Radu, G. L. Chem. Pap. 2014, 68 (8), 1022.
15. [15]
  Koh, A. J.; Yasur-Landau, A.; Cline, E. H. Plos one 2014, 9 (8), e106406.
16. [16]
  Garnier, N.; Valamoti, S. M. J. Archaeol. Sci. 2016, 74, 195.
17. [17]
  McGovern, P. E.; Hall, G. R. J. Archaeol. Method Th. 2016, 23 (2), 592.
18. [18]
  Manzano, E.; Cantarero, S.; Garcıa, A.; Adroher, A.; Vılchez, J. L. Microchem J. 2016, 129, 286.
19. [19]
  Pecci, A.; Innocenti, E. D.; Giorg, G.; Ontiveros, M. A. C.; Cantini, F.; Potrony, E. S.; Alós, C.; Miriello, D. Archaeol. Anthropol. Sci. 2016, 8 (4), 879.
20. [20]
  Wang, J.; Liu, L.; Ball, T.; Yu, L.; Li, Y.; Xing, F. Proc. Natl. Acad. Sci. U. S. A. 2016, 113 (23), 6444.
21. [21]
  Zhang, T.; Xu, S.; Li, Y.; Wen, R.; Yang, G. J. Archaeol. Sci. 2018, 142, 175.
22. [22]
  Perruchini, E.; Glatz, C.; Hald, M. M.; Casana, J.; Toney, J. M. J. Archaeol. Sci. 2018, 100, 176.
23. [23]
  Pecci, A.; Borgna, E.; Mileto, S.; Longa, E. D.; Bosi, G.; Florenzano, A.; Mercuri, A. M.; Corazza, S.; Marchesini, M.; Vidale, M. J. Archaeol. Sci. 2020, 123, 105256.
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