Citation: Shuo Cao, Honglin Zeng, Jiaxin Zhou, Siyuan Shao, Fengrui Liu, Haoran Chen, Fang Chen. Determination of SO₂ in Food by Flow Injection Chemiluminescence with Carbon Dots as Sensitizer[J]. University Chemistry, ;2023, 38(2): 170-176. doi: 10.3866/PKU.DXHX202204064 shu

Determination of SO₂ in Food by Flow Injection Chemiluminescence with Carbon Dots as Sensitizer

School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

Corresponding author: Fang Chen, fchen@hust.edu.cn
Received Date: 20 April 2022

The detection of sulfur dioxide is crucial for food safety. In this study, a flow injection chemiluminescence method for the determination of sulfur dioxide in food was established by using an acidic potassium permanganate sulfite system with carbon dots (CDs) as the sensitizer. Under the optimum experimental conditions, the linear range, and the detection limit of the method were 1.0 × 10^-5–3.0 × 10^-4 mol·L^-1 and 7.79 × 10^-6 mol·L^-1, respectively. The experiment is suitable for teaching instrument analysis to undergraduates. This experiment enables students to master the principle and application of chemiluminescence and flow injection analysis, learn the basic methods of scientific research, and improve their thinking ability.
- Flow injection,
- Chemiluminescence,
- Carbon dots,
- Sulfur dioxide,
- Food analysis
1. [1]
2. [2]
3. [3]
  Molaei, M. J. Anal. Methods 2020, 12, 1266.
4. [4]
  Ge, G. L.; Li, L.; Wang, D.; Chen, M. J.; Zeng, Z. Y.; Xiong, W.; Wu, X.; Guo, C. J. Mater. Chem. B 2021, 9, 6553.
5. [5]
  Duan, Y.; Huang, Y.; Chen, S.; Zuo, W.; Shi, B. ACS Omega 2019, 4, 9911.
6. [6]
  Chen, J. Q.; Shu, J.; Chen, J.; Cao Z. R.; Xiao, A.; Yan, Z. Y. Luminescence 2019, 32, 277.
7. [7]
  Wang, J. B.; Han, S. Q.; Fan, Z. Y.; Chen, Y. Y.; Zhang, L. F.; Jiang, F. Y. J. Chin. Chem. Soc. 2017, 64, 486.
8. [8]
  Li, Y.; Han, S. Q. Microchem. J. 2020, 154, 104638.
9. [9]
  Yamada, M.; Nakada, T.; Suzuki, S. Anal. Chim. Acta 1983, 147, 401.
10. [10]
11. [11]
12. [12]
  Yu, F. S.; Lin. Li.; Chen, F.; Liu, W. Z. Anal. Lett. 2010, 43, 357.
13. [13]
  Yi, L.; Zhao, H. C.; Chen, S. L.; Jin, L. P.; Zheng, D. D.; Wu, Z. L. Talanta 2003, 61, 403.
14. [14]
  Song, H. J.; Su, Y. Y.; Zhang, L. C.; Lv, Y. Luminescence 2019, 34, 530.
15. [15]
  Wang, D. M.; Lin, K. L.; Huang, C. Z. Luminescence 2019, 34, 4.
16. [16]
17. [17]
  Stauff, J.; Jaeschke, W. Atmos. Environ. 1967, 9, 1038.
18. [18]
19. [19]
  Liang, Y.; Zhang, H.; Zhang, Y.; Chen, F. Anal. Methods 2015, 7, 7540.
20. [20]
21. [21]
  Li, Y. H.; Lu J. R. Anal. Chim. Acta 2006, 577 (1), 107.
22. [22]
  Adcock, J. L.; Francis, P. S.; Barnett, N. W. Anal. Chim. Acta 2009, 652 (1-2), 303.
23. [23]
  Khataee, A.; Lotfi, R.; Hasanzadeh, A.; Iranifam, M.; Joo, S. W. Spectrochim. Acta A 2016, 154, 243.
24. [24]
  Lin, Z.; Xue, W.; Chen, H.; Lin, J. M. Anal. Chem. 2011, 83 (21), 8245.
25. [25]
  Jeon, C. W.; Khan, M. A.; Lee, S. H.; Karim, M. M.; Lee, H. K.; Suh, Y. S.; Alam, S. M.; Chung, H. Y. J. Fluoresc. 2008, 18 (5), 843.
1. [1]
  Borong Yu , Huijiao Zhang , Xinyu Zhang , Xiaoying Li , Shuming Chen , Zhangang Han . The Blue Elf in the Dark: Gradient Science Popularization Experiments on Chemiluminescence. University Chemistry, 2024, 39(9): 295-303. doi: 10.12461/PKU.DXHX202403107
2. [2]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
3. [3]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
4. [4]
  Yue WANG , Zhizhi GU , Jingyi DONG , Jie ZHU , Cunguang LIU , Guohan LI , Meichen LU , Jian HAN , Shengnan CAO , Wei WANG . Effects of kelp-derived carbon dots on embryonic development of zebrafish. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1209-1217. doi: 10.11862/CJIC.20230423
5. [5]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
6. [6]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
7. [7]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
8. [8]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
9. [9]
  Li'na ZHONG , Jingling CHEN , Qinghua ZHAO . Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 709-718. doi: 10.11862/CJIC.20240280
10. [10]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
11. [11]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
12. [12]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
13. [13]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
14. [14]
  Xiaomei Ning , Liang Zhan , Xiaosong Zhou , Jin Luo , Xunfu Zhou , Cuifen Luo . Preparation and Electro-Oxidation Performance of PtBi Supported on Carbon Cloth: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 217-224. doi: 10.3866/PKU.DXHX202401085
15. [15]
  Tingting Yu , Si Chen , Lianglong Sun , Tongtong Shi , Kai Sun , Xin Wang . Comprehensive Experimental Design for the Photochemical Synthesis, Analysis, and Characterization of Difluoropyrroles. University Chemistry, 2024, 39(11): 196-203. doi: 10.3866/PKU.DXHX202401022
16. [16]
  Hongyan Feng , Weiwei Li . Reflections on the Safety of Chemical Science Popularization Activities. University Chemistry, 2024, 39(9): 379-384. doi: 10.12461/PKU.DXHX202404087
17. [17]
  Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, 2024, 39(9): 248-253. doi: 10.3866/PKU.DXHX202308074
18. [18]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
19. [19]
  Tingting Jiang , Jing Chang . Application of Ideological and Political Education in Chemical Analysis Experiment under the Background of Emerging Engineering Education: Taking the Redox Titration Experiment as an Example. University Chemistry, 2024, 39(2): 168-174. doi: 10.3866/PKU.DXHX202308007
20. [20]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(833)
HTML views(80)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Determination of SO2 in Food by Flow Injection Chemiluminescence with Carbon Dots as Sensitizer

Metrics

通讯作者: 陈斌, bchen63@163.com

Determination of SO₂ in Food by Flow Injection Chemiluminescence with Carbon Dots as Sensitizer