Home

Citation: Yiying Yang, Peng Liu, Siwei Bi, Dongju Zhang. New Type of Catalytic Tandem Reactions Characterized by “Process Separation”[J]. University Chemistry, ;2023, 38(1): 97-102. doi: 10.3866/PKU.DXHX202202067 shu

New Type of Catalytic Tandem Reactions Characterized by “Process Separation”

1.
School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China;
2.
School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, Shandong Province, China

Received Date: 28 February 2022

Based on the latest research results in the field of synthetic chemistry, a new type of catalytic tandem reactions characterized by “separation of the catalytic processes” have been developed. In such reactions, each step of the reaction takes place successively in time, and each step is independent and does not affect the others. Taking a typical reaction as an example, in this paper, the basic characteristics of this type of reaction and its importance in the field of synthetic chemistry are introduced, and a theoretical model is established to understand the kinetic characteristics of this type of reaction based on the results of quantum chemistry calculations found in the literature.
- Tandem reaction,
- Catalysis,
- Process separation,
- Theoretical model
1. [1]
  Abou-Shehada, S.; Williams, J. M. J. Nat. Chem. 2014, 6, 12.
2. [2]
  Ball, L. T.; Corrie, T. J. A.; Cresswell, A. J.; Lloyd-Jones, G. C. ACS Catal. 2020, 10, 10420.
3. [3]
  Fogg, D. E.; dos Santos, E. N. Coord. Chem. Rev. 2004, 248, 2365.
4. [4]
5. [5]
6. [6]
  Atkins, P.; de Paula, J.; Keeler, J. Atkins’ Physical Chemistry,11th ed.; Oxford University Press: Oxford, UK, 2018; pp. 1945−1948.
7. [7]
  Rochat, R.; Yamamoto, K.; Lopez, M. J.; Nagae, H.; Tsurugi, H.; Mashima, K. Chem. Eur. J. 2015, 21, 8112.
8. [8]
  Tokimizu, Y.; Oishi, S.; Fujii, N.; Ohno, H. Angew. Chem. Int. Ed. 2015, 54, 7862.
9. [9]
  Li, L.; Herzon, S. B. Nat. Chem. 2014, 6, 22.
10. [10]
  Wang, J.; Qi. T.; Li, Z.; She, W.; Li, X.; Li, J.; Yan, P.; Li, W.; Li, G. J. Catal. 2019, 376, 106.
11. [11]
  Smith, C. A.; Motika, S. E.; Wojtas, L.; Shi, X. Chem. Commun. 2017, 53, 2315.
12. [12]
  Yao, B.; Wang, Q.; Zhu, J. Chem. Eur. J. 2015, 21, 7413.
13. [13]
  Kaeffer, N.; Larmier, K.; Alexey Fedorov, A.; Copéret, C. J. Catal. 2018, 364, 437.
14. [14]
  Kondoh, A.; Terada, M. Org. Lett. 2018, 20, 5309.
15. [15]
  Duan, Y.; Liu, Y.; Bi, S.; Ling, B.; Jiang, Y.; Liu, P. J. Org. Chem. 2016, 81, 9381.
1. [1]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024
2. [2]
  Jie ZHAO , Sen LIU , Qikang YIN , Xiaoqing LU , Zhaojie WANG . Theoretical calculation of selective adsorption and separation of CO₂ by alkali metal modified naphthalene/naphthalenediyne. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 515-522. doi: 10.11862/CJIC.20230385
3. [3]
  Jie ZHAO , Huili ZHANG , Xiaoqing LU , Zhaojie WANG . Theoretical calculations of CO₂ capture and separation by functional groups modified 2D covalent organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 275-283. doi: 10.11862/CJIC.20240213
4. [4]
  Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
5. [5]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
6. [6]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
7. [7]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
8. [8]
  Yue Zhao , Yanfei Li , Tao Xiong . Copper Hydride-Catalyzed Nucleophilic Additions of Unsaturated Hydrocarbons to Aldehydes and Ketones. University Chemistry, 2024, 39(4): 280-285. doi: 10.3866/PKU.DXHX202309001
9. [9]
  Hong Lu , Yidie Zhai , Xingxing Cheng , Yujia Gao , Qing Wei , Hao Wei . Advancements and Expansions in the Proline-Catalyzed Asymmetric Aldol Reaction. University Chemistry, 2024, 39(5): 154-162. doi: 10.3866/PKU.DXHX202310074
10. [10]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
11. [11]
  Yuanyi Lu , Jun Zhao , Hongshuang Li . Silver-Catalyzed Ring-Opening Minisci Reaction: Developing a Teaching Experiment Suitable for Undergraduates. University Chemistry, 2024, 39(11): 225-231. doi: 10.3866/PKU.DXHX202401088
12. [12]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-. doi: 10.3866/PKU.WHXB202408015
13. [13]
  Hongting Yan , Aili Feng , Rongxiu Zhu , Lei Liu , Dongju Zhang . Reexamination of the Iodine-Catalyzed Chlorination Reaction of Chlorobenzene Using Computational Chemistry Methods. University Chemistry, 2025, 40(3): 16-22. doi: 10.12461/PKU.DXHX202403010
14. [14]
  Aili Feng , Xin Lu , Peng Liu , Dongju Zhang . Computational Chemistry Study of Acid-Catalyzed Esterification Reactions between Carboxylic Acids and Alcohols. University Chemistry, 2025, 40(3): 92-99. doi: 10.12461/PKU.DXHX202405072
15. [15]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
16. [16]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
17. [17]
  Ke QIAO , Yanlin LI , Shengli HUANG , Guoyu YANG . Advancements in asymmetric catalysis employing chiral iridium (ruthenium) complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2091-2104. doi: 10.11862/CJIC.20240265
18. [18]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
19. [19]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
20. [20]
  Ruilin Han , Xiaoqi Yan . Comparison of Multiple Function Methods for Fitting Surface Tension and Concentration Curves. University Chemistry, 2024, 39(7): 381-385. doi: 10.3866/PKU.DXHX202311023

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(899)
HTML views(170)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return