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Citation: Guanghui Chen, Xinming Du, Wangqiang Lin, Li Ma, Kun Jiang. 针对原子轨道对称性匹配原则的分层次教学研究[J]. University Chemistry, ;2022, 37(11): 211207. doi: 10.3866/PKU.DXHX202112073 shu

针对原子轨道对称性匹配原则的分层次教学研究

1.
Department of Chemistry, College of Science, Shantou University, Shantou 515063, Guangdong Province, China;
2.
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;
3.
Department of Natural Science, Shantou Polytechnic, Shantou 515041, Guangdong Province, China

Corresponding author: Li Ma, mali@sjtu.edu.cn
Received Date: 27 December 2021

在化学专业本科生普通化学、结构化学以及研究生量子化学课程教学中，都不同程度地涉及分子轨道理论。其中组成分子轨道的原子轨道的对称性匹配问题是重要的知识点，但很多学生对此认识不清。针对这一知识点，我们根据学生不同阶段的知识基础，采用逐层递进的方法开展教学：在普通化学教学中，采用原子轨道的对称元素来解释；在结构化学课程中，则从群表示理论的角度来阐述；而在量子化学教学中，则以硫化氢分子为例，利用Roothaan方程求解分子轨道系数进行验证。由浅入深，引导学生在不同层次理解原子轨道对称性匹配组合成分子轨道原理。
- Symmetry matching of atomic orbital,
- Molecular orbital theory,
- Multi-level teaching
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