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Citation: Hanyue Gong, Houguang Wang, Chengbin Xu, Fuping Tian, Yanjuan Zhang. β分子筛的酸性和孔道对α-蒎烯催化转化性能的影响[J]. University Chemistry, ;2022, 37(5): 211202. doi: 10.3866/PKU.DXHX202112028 shu

β分子筛的酸性和孔道对α-蒎烯催化转化性能的影响

1.
School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, China;
2.
Zhang Dayu School of Chemistry, Dalian University of Technology, Dalian 116024, Liaoning Province, China

Corresponding author: Yanjuan Zhang, zhangyanjuan@dlut.edu.cn
Received Date: 7 December 2021

高等物理化学实验是我校理科化学专业学生的必修课，催化剂的制备与表征是其中不可或缺的部分。本实验是对高等物理化学教学实验“NH₃-TPD法分析材料的酸性质”及“催化剂活性及选择性的测定”的改进，改进后方案将原实验方案中考察单一催化剂上反应物在不同反应温度和反应时间下的转化率和选择性，更改为具有不同孔道结构和酸量的三种催化剂在同一反应条件下的催化性能对照，同时结合仪器分析实验“N₂物理吸附”等相关化学实验，使学生连贯地学习催化剂的制备、改性与表征技术，更清晰地认识影响催化剂催化性能的影响因素。旨在使学生将在多门课程中所学习到的理论知识融会贯通，深入了解β分子筛在较大尺寸反应物分子的转化反应中发挥催化作用的原理。
- Zeolite β,
- Acid property,
- Porous structure,
- Isomerization of α-pinene
1. [1]
  Higgins, J. B.; LaPierre, R. B.; Schlenker, J. L.; Rohrman, A. C.; Wood, J. D.; Kerr, G. T.; Rohrbaugh, W. J. Micropor. Mesopor. Mater. 1988, 8, 446.
2. [2]
  Davis, M E. Nature 2002, 417, 813.
3. [3]
  Ogura, M.; Shinomiya, S.Y.; Tateno, J.; Nara, Y.; Nomura, M.; Kikuchi, E.; Matsukata, M. Appl. Catal. A Gen. 2001, 219 (1-2), 33.
4. [4]
  Wei, X.; Smirniotis, P. G. Micropor. Mesopor. Mater. 2006, 97 (1-3), 97.
5. [5]
  Groen, J. C.; Sano, T.; Moulijin, J. A. J. Catal. 2007, 251 (1), 21.
6. [6]
  Groen, J. C.; Abello, S.; Villaescusa, L. A. Micropor. Mesopor. Mater. 2008, 114 (1-3), 93.
7. [7]
8. [8]
  Corma, A.; lborra, S.; Velty, A. Chem. Rev. 2007, 107, 2411.
9. [9]
  Özkan, F.; Gündüz, G.; Akpolat, O.; Besun, N.; Murzin, D. Y. Chem. Eng. J. 2003, 91 (2-3), 257.
1. [1]
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2. [2]
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