Citation: Xiang Yang, Aijuan Han, Junfeng Liu. 笑傲江湖之金属有机骨架材料[J]. University Chemistry, ;2021, 36(10): 210708. doi: 10.3866/PKU.DXHX202107086 shu

笑傲江湖之金属有机骨架材料

State Key Laboratory of Chemical Resource Engineering, College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: Aijuan Han, hanaijuan@mail.buct.edu.cn
Received Date: 25 July 2021

金属有机骨架材料（MOFs）是一种具有三维周期性网状结构的化合物。由于MOFs具有孔隙率高、比表面积大和孔径可调节等特点，在吸附分离方面表现出极佳的性能。本文运用拟人化的手法，向读者展示MOFs的性质、结构调控和在吸附分离方面的应用。
- MOFs,
- Gas adsorption,
- Liquid phase adsorption
1. [1]
  Li, H.; Eddaoudi, M.; O'keeffe, M.; Yaghi, O. M. Nature 1999, 402(6759), 276.
2. [2]
  Cavka, J. H.; Jakobsen, S.; Olsbye, U.; Guillou, N.; Lamberti, C.; Bordiga, S.; Lillerud, K. P. J. Am. Chem. Soc. 2008, 130(42), 13850.
3. [3]
  Furukawa, H.; Cordova, K. E.; O'Keeffe, M.; Yaghi, O. M. Science 2013, 341(6149), 123044.
4. [4]
  Férey, G.; Mellot-Draznieks, C.; Serre, C.; Millange, F.; Dutour, J.; Surblé, S.; Margiolaki, I. Science 2005, 309(5743), 2040.
5. [5]
  Park, K. S.; Ni, Z.; Côté, A. P.; Choi, J. Y.; Huang, R.; Uribe-Romo, F. J.; Chae, H. K.; O'Keeffe, M.; Yaghi, O. M. P. Natl. Acad. Sci. USA 2006, 103(27), 10186.
6. [6]
  Chui, S. S. Y.; Lo, S. M. F.; Charmant, J. P. H.; Orpen, A. G.; Williams, I. D. Science 1999, 283(5405), 1148.
7. [7]
  Farha, O. K.; Eryazici, I.; Jeong, N. C.; Hauser, B. G.; Wilmer, C. E.; Sarjeant, A. A.; Snurr, R. Q.; Nguyen, S. T.; Yazaydin, A. Ö.; Hupp, J. T. J. Am. Chem. Soc. 2012, 134(36), 15016.
8. [8]
  Rosi, N. L.; Eckert, J.; Eddaoudi, M.; Vodak, D. T.; Kim, J.; O'Keefe, M.; Yaghi, O. M. Science 2003, 300(5622), 1127.
9. [9]
  Tibbetts, G. G.; Meisner, G. P.; Olk, C. H. Carbon 2001, 39(15), 2291.
10. [10]
  Jia, M.; Feng, Y.; Qiu, J.; Zhang, X. F.; Yao, J. Sep. Purif. Technol. 2019, 213, 63.
11. [11]
  Liu, W.; Huang, J.; Yang, Q.; Wang, S.; Sun, X.; Zhang, W.; Liu, J.; Huo, F. Angew. Chem. Int. Ed. 2017, 129(20), 5512.
12. [12]
  Wang, K.; Li, C.; Liang, Y.; Han, T.; Huang, H.; Yang, Q.; Liu, D.; Zhong, C. Chem. Eng. J. 2016, 289, 486.
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