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Citation: Mei Pan, Chaojie Li, Yajun Hou, Chengyong Su. Synthesis and Physical Chemistry Property Study of a Fe(II)-Pd(II) Heteronuclear Metal-Organic Cag: A New Comprehensive Chemistry Experiment[J]. University Chemistry, ;2021, 36(6): 200604. doi: 10.3866/PKU.DXHX202006045 shu

Synthesis and Physical Chemistry Property Study of a Fe(II)-Pd(II) Heteronuclear Metal-Organic Cag: A New Comprehensive Chemistry Experiment

Mei Pan ^1,, ,
Chaojie Li ^1,2 ,
Yajun Hou ¹ ,
Chengyong Su ¹

1.
School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, China;
2.
Zhuhai Fourth Middle School, Zhuhai 519015, Guangdong Province, China

Corresponding author: Mei Pan, panm@mail.sysu.edu.cn
Received Date: 12 June 2020

A Fe(II)-Pd(II) heteronuclear metal-organic cages (MOC-42) is obtained by stepwise synthesis. The solution structure of MOC-42 is characterized by NMR, and the decomposition kinetics is studied by UV-Vis absorption spectra. This new comprehensive chemistry experiment is appropriate in difficulty, and the studying methods are various, which enables students to flexibly apply the existing basic chemical knowledge and modern instrument techniques. It is beneficial to train the ability of initiative thinking and practice competency of the students.
- Metal-organic cage,
- Stepwise assembly,
- Decomposition kinetics,
- Physical chemistry property
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  Hou, Y. J.; Wu, K.; Wei, Z. W.; Li, K.; Lu, Y. L.; Zhu, C. Y.; Wang, J. S.; Pan, M.; Jiang, J. J.; Li, G. Q.; et al. J. Am. Chem. Soc. 2018, 140 (51), 18183.
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