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Citation: YU Xiwen, YANG Yunhui, WANG Congyang. Manganese-Enabled Synthetic Chemistry and Applications[J]. University Chemistry, ;2019, 34(12): 64-72. doi: 10.3866/PKU.DXHX201909043 shu

Manganese-Enabled Synthetic Chemistry and Applications

YU Xiwen ^1,2, ,
YANG Yunhui ^1,2,3 ,
WANG Congyang ^1,2,3

1.
Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2.
University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3.
Physical Science Laboratory, Huairou National Comprehensive Science Center, Beijing 101400, P. R. China

Received Date: 26 September 2019

Photosynthesis is the most important synthetic reaction in nature, the O₂-evolution center of which contains the key Mn-O-Ca structure motif. Manganese features earth abundance, low toxicity, rich oxidative states, and unique reactivities, which makes it of great importance and hold huge potentials to achieve new synthesis unavailable by nature. In this paper, the history of manganese-enabled synthetic chemistry and its recent applications in inorganic electrochemistry and organic synthesis are reviewed briefly.
- Manganese,
- Manganese oxides,
- Manganese carbonyl complexes,
- Synthetic chemistry
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