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Citation: YANG Tianyi, ZENG Qing, WANG Gan, MIAO Yidan. Application of Arrow-Pushing in the Disproportionation of Halogen Oxoanions[J]. University Chemistry, ;2019, 34(3): 68-76. doi: 10.3866/PKU.DXHX201807013 shu

Application of Arrow-Pushing in the Disproportionation of Halogen Oxoanions

1.
College of Life Sciences, Peking University, Beijing 100871, P. R. China;
2.
College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China;
3.
College of Yuanpei, Peking University, Beijing 100871, P. R. China

Received Date: 5 July 2018

The article uses the disproportionation of chlorate and hypobromite as examples to analyze the application of arrow-pushing in the disproportionation of halogen oxoanions. Based on the experimental results, we have discussed the rationality of each possible mechanism we proposed based on electronic structure methods. All these efforts are put to demonstrate the way to introduce basic organic-style arrow-pushing into inorganic field.
- Halogen oxoanion,
- Disproportionation,
- Inorganic reaction,
- Mechanism
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2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
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