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Citation: MA Ming-Zhe, CAO Ruo-Chen, WU Jiang-Bo, XU Jia-Yu, BIAN Jiang. Inorganic Reaction Mechanism of Chalcogen-Chalcogen Bond[J]. University Chemistry, ;2017, 32(10): 75-83. doi: 10.3866/PKU.DXHX201703017 shu

Inorganic Reaction Mechanism of Chalcogen-Chalcogen Bond

1.
College of Yuanpei, Peking University, Beijing 100871, P. R. China;
2.
College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

This paper explains some inorganic reaction mechanisms of oxidation-reduction reactions involving chalcogen-chalcogen single bond, according to thermodynamic and kinetic data. DFT method is used to verify proposed mechanisms and conjectures by Gaussian09 program. All these efforts are put to demonstrate some general patterns in inorganic reaction mechanisms.
- Inorganic reaction mechanism,
- Chalcogen,
- Chalcogen-chalcogen bond,
- Oxidation-reduction reaction
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