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Citation: WANG Zhao-Xia, ZHAO Mei-Xin, XU Sheng, LUO Qian-Fu. Brief Analysis of the Stability of Common Carbocations in the Teaching of University Chemistry[J]. University Chemistry, ;2017, 32(7): 54-59. doi: 10.3866/PKU.DXHX201702017 shu

Brief Analysis of the Stability of Common Carbocations in the Teaching of University Chemistry

Department of Chemistry, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai 200237, P. R. China

The discussion on the stability of different carbocations is one of the key topics in the teaching of organic chemistry at university.However,the results in one text or document often disagreed with those of the others.In this paper,we present the reasonable comparison and explanation about the different kinds of carbocations based on the comprehensive analysis of references,data and theory.
- Carbocations,
- Stability,
- Hybridization,
- Electronic effect
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
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