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Citation: WANG Jing-Zun. How to Interpret EI-MS Spectra[J]. University Chemistry, ;2016, 31(4): 49-54. doi: 10.3866/PKU.DXHX20160449 shu

How to Interpret EI-MS Spectra

WANG Jing-Zun ^,

1.
Beijing Institute of Microchemistry, Beijing 100091, P. R. China

Corresponding author: WANG Jing-Zun,

EI-MS is a frequently adopted technique which can provide rich information in compound structures. The following properties can be retrieved directly from the mass spectrum of an unknown compound, including the molecular or fragment ion peak, odd or even charge and mass, elemental numbers (C, N, Si, Cl, Br, etc.). It is a basic skill to be able to acquire the aforementioned information from the mass spectrum.
- EI-MS Spectrum,
- Spectral interpretation
1. [1]
  [1] McLafferty, F.W. Interpretation of Mass Spectra; Mill Valley: CA, 1980; pp 134－135.
2. [2]
  [2] 王敬尊, 瞿慧生. 复杂样品的综合分析. 北京: 化工出版社, 2000: 394－397.
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