Citation:
LIU Xu-Dong, FAN Hui-Li, XIAO Jun-Ping. Study on the Heavy Atom Effect on 13C NMR Spectroscopy[J]. University Chemistry,
;2016, 31(3): 32-36.
doi:
10.3866/PKU.DXHX20160332
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The heavy atom effect on 13C NMR chemical shifts is described. We analyzed and summarized the impact of bromine and iodine on the chemical shifts of carbon with different hybrid states and environment.
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Keywords:
- 13C NMR spectroscopy,
- Heavy atom effect,
- Bromine,
- Iodine
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[1]
[1] McClure, D. S. J. Chem. Phys. 1949, 17(10), 905.
-
[2]
[2] Yuster, P.;Weisman, S. L. J. Chem. Phys. 1949, 17(12), 1182.
-
[3]
[3] Koziar, J. C.; Cowan, D. O. Acc. Chem. Res. 1978, 11, 334.
-
[4]
[4] 刘海洋, 郭平叶, 江柏荣, 应晓, 廖世军, 麦乃歧, 张启光. 高等学校化学学报, 2006, No. 7, 1363.
-
[5]
[5] 张慧娟, 冯娟, 孙照勇, 艾希成, 张建平, 张兴康, 虞忠衡, 韩士田, 刘彦钦, 吴银素. 高等学校化学学报, 2003, No. 11, 2069.
-
[6]
[6] 梁晓琴, 廖显威. 四川师范大学学报(自然科学版), 2001, No. 3, 274.
-
[7]
[7] 宁永成. 有机化合物结构鉴定与有机波谱学. 第2版. 北京:科学出版社, 2002.
-
[8]
[8] Pretsch, E.; Buhlmann, P.; Badertscher, M. 有机化合物结构鉴定——光谱数据手册. 北京:科学出版社, 2012.
-
[9]
[9] Cvengros, J.; Stolz, D.; Togni, A. Synthesis 2009, 2818.
-
[10]
[10] Liu, C.-Y.; Ren, H. J.; Knochel, P. Org. Lett. 2006, 8(4), 617.
-
[11]
[11] Tachinami, T.; Nishimura, T.; Ushimaru, R.; Noyori, R.; Naka, H. J. Am. Chem. Soc. 2013, 135(1), 50.
-
[12]
[12] Kulbitski, K.; Nisnevich, G.; Gandelman, M. Adv. Synth. Catal. 2011, 353(9), 1438.
-
[13]
[13] Hashmi, A. S. K.; Ramamurthi, T. D.; Todd, M. H.; Tsang, A. S.-K.; Graf, K. Aust. J. Chem. 2010, 63(12), 1619.
-
[14]
[14] Jakab, G.; Hosseini, A.; Hausmann, H.; Schreiner, P. R. Synthesis 2013, 45(12), 1635.
-
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