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Citation: YANG Ren, WANG Jinxing, ZHANG Yue, WANG Qing, YUE Xuanfeng. Gas chromatographic determination of trace carbon monoxide and carbon dioxide in sulfur hexafluoride and its application to probing potential breakdown of high-voltage circuit breaker[J]. Chinese Journal of Chromatography, ;2020, 38(6): 702-707. doi: 10.3724/SP.J.1123.2019.11012 shu

Gas chromatographic determination of trace carbon monoxide and carbon dioxide in sulfur hexafluoride and its application to probing potential breakdown of high-voltage circuit breaker

YANG Ren ^1,, ,
WANG Jinxing ² ,
ZHANG Yue ³ ,
WANG Qing ³ ,
YUE Xuanfeng ^3,,

1.
Electric Power Research Institute of State Grid Shaanxi Electric Power Company, Xi'an 710048, China;
2.
State Grid Shaanxi Electric Power Company, Xi'an 710048, China;
3.
Key Laboratory of Analytical Chemistry for Life Science of Shaanxi Province, School of Chemistry and Chemical Engineering of Shaanxi Normal University, Xi'an 710062, China

Corresponding author: YANG Ren, YUE Xuanfeng,
Received Date: 22 November 2019

Fund Project: Fund for the Transformation of Scientific and Technological Achievements of Central Universities (No. GK201806003)

A reliable gas chromatography-flame ionization detector (GC-FID) method was developed for the accurate determination of trace CO and CO₂ in high concentration of SF₆. Using a combination of dual Porapak Q chromatographic columns with valve switching, SF₆ was separated from the tested samples and blown out of the detection system, with the aim of ruling out the possibility of conversion column poisoning. Meanwhile, CO and CO₂ were on-line separated and subsequently converted to CH₄ in the presence of a nickel catalyst to increase the sensitivity for the determination of carbon-borne gases. The results showed that neither gas interfered with the determination of the other. Satisfactory linearities were achieved in the range 2-500 μL/L for both CO and CO₂, with highly accurate and reproducible determination (RSD<2%). The developed GC-FID method is applicable to the determination of gases lodged in high-voltage circuit breakers toward the analysis of trace CO and CO₂, thus providing a tool for probing the potential breakdown of SF₆-insulated equipment.
- gas chromatography (GC),
- carbon monoxide,
- carbon dioxide,
- sulfur hexafluoride,
- breakdown of circuit breaker
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