Citation: YANG Chengxiong, YANG Xueqing, YAN Xiuping. Preparation of metal-organic framework MIL-101(Cr) incorporated polymer monolithic column for on-line solid-phase extraction of phenols[J]. Chinese Journal of Chromatography, ;2019, 37(8): 824-830. doi: 10.3724/SP.J.1123.2019.01023 shu

Preparation of metal-organic framework MIL-101(Cr) incorporated polymer monolithic column for on-line solid-phase extraction of phenols

1.
College of Chemistry, Research Center for Analytical Science, Nankai University, Tianjin 300071, China;
2.
Institute of Analytical Food Safety, School of Food Science and Technology, Jiangnan University, Wuxi 214122, China

Received Date: 29 January 2019

Fund Project: National Natural Science Foundation of China (Nos. 21775056, 21777074).

A metal-organic framework (MOF) MIL-101(Cr) incorporated polymer monolithic column was prepared, and a method was developed for the determination of 4-nitrophenol, 3-methylphenol, 2-nitrophenol and 2,4-dichlorophenol in water samples by on-line solid phase extraction (SPE) coupled with high performance liquid chromatography (HPLC). Effects of sample solution pH values, sample loading time, sample loading flow rates and desorption time on the on-line SPE of phenols were investigated. Under the optimized extraction conditions, large enhancement factors, wide linearity range, good precisions and low limits of detection were achieved. The results showed that the incorporation of MOFs in porous polymer monolith to fabricate MOF-incorporated monolith is one of the best ways to promote and expand the application of MOFs in on-line SPE.
- on-line solid phase extraction (on-line SPE),
- metal-organic frameworks (MOFs),
- monolithic column,
- phenols
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