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Citation: ZHANG Yueqin, GAO Guohua, YANG Keyong, ZONG Baoning, XU Guangtong. Qualitative analysis of compositions of anthraquinone series working solution by gas chromatography-mass spectrometry[J]. Chinese Journal of Chromatography, ;2019, 37(4): 432-437. doi: 10.3724/SP.J.1123.2018.11036 shu

Qualitative analysis of compositions of anthraquinone series working solution by gas chromatography-mass spectrometry

SINOPEC Research Institute of Petroleum Processing, Beijing 100083, China

Received Date: 25 November 2018

Fund Project: National Key Research and Development Program of China (No. 2016YFB031600).

A method for the qualitative analysis of compositions of anthraquinone working solution (WS)/hydrogenated working solution (HWS) by gas chromatography-mass spectrometry (GC-MS) was developed. The composition of ethylanthraquinone (eAQ) WS/HWS was identified by GC-MS. Then the samples of amylanthraquinone (AAQ) WS/HWS were analyzed by GC-MS. Combined with the reaction mechanism, the composition of AAQ WS/HWS was inferred. The list of the degradation as well as the intermediate products in the industrial synthesis of H₂O₂ in anthraquinone WS was generated, and the information obtained regarding the composition of the anthraquinone WS/HWS was helpful in identifying and removing the unacceptable degradation products.
- gas chromatography-mass spectrometry (GC-MS),
- qualitative analysis,
- ethylanthraquinone,
- amylanthraquinone,
- work solution (WS),
- hydrogenated work solution (HWS)
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