Citation: QIN Fu, DENG Quandao, LI Yong, HUANG Daxin, WANG Wenlong. Rapid determination of 55 fungicides in siraitia grosvenoriis by QuEChERS and high performance liquid chromatography-tandem mass spectrometry[J]. Chinese Journal of Chromatography, ;2017, 35(11): 1129-1136. doi: 10.3724/SP.J.1123.2017.07019 shu

Rapid determination of 55 fungicides in siraitia grosvenoriis by QuEChERS and high performance liquid chromatography-tandem mass spectrometry

QIN Fu ^1, ,
DENG Quandao ² ,
LI Yong ¹ ,
HUANG Daxin ¹ ,
WANG Wenlong ¹

1.
Inspection and Quarantine Technology Center of Guangxi Entry-Exit Inspection and Quarantine Bureau, Nanning 530021, China;
2.
Guilin Entry-Exit Inspection and Quarantine Bureau, Guilin 541004, China

Received Date: 23 July 2017

Fund Project: Science and Technology Innovation Capability and Conditional Construction Plan of Guangxi Zhuang Autonomous Region (Nos. 14123006-15, 1598025-1).

A method for the determination of 55 fungicides in siraitia grosvenoriis by QuEChERS and high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) was established. The samples were extracted with acetonitrile containing 1%(v/v) acetic acid, then dehydrated by anhydrous magnesium sulfate and purified by anhydrous sodium sulfate, N-propyl ethylenediamine (PSA) and C18. Then, 95% (v/v) acetonitrile aqueous solution (organic phase) and water (aqueous phase), both containing 0.005 mol/L ammonium formate and 0.01% (v/v) formic acid, were used as mobile phases with gradient elution. The compounds were tested by positive electrospray ion source (ESI⁺) and dynamic multiple reaction monitoring (DMRM) mode. Fifty-five fungicides were quantified by external standard method considering matrix effects. The correlation coefficients (R²) were greater than 0.99, which indicated that the linear dependence of the 55 fungicides were good in the range of 1.0-100.0 μg/kg. The LODs (S/N>3) and LOQs (S/N>10) of all the fungicides were 1.0 μg/kg and 10.0 μg/kg, respectively. The recoveries were in the range of 76.96%-118.45% and the relative standard deviations (RSDs) ranged from 3.44% to 19.63% (n=6). This method has the advantages of rapidity, accuracy and sensitivity for the high-throughput detection of fungicides residues in siraitia grosvenoriis.
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
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