Citation: SUN Yuming, WANG Yueyue, CAI Rui, ZHANG Hua, WANG Yulin. Identification of the chemical compositionsof Verbena officinalis L. extract by high performance liquid chromatography-photodiode array-high resolution mass spectrometry[J]. Chinese Journal of Chromatography, ;2017, 35(9): 987-994. doi: 10.3724/SP.J.1123.2017.05010 shu

Identification of the chemical compositionsof Verbena officinalis L. extract by high performance liquid chromatography-photodiode array-high resolution mass spectrometry

SUN Yuming ^1, ,
WANG Yueyue ¹ ,
CAI Rui ¹ ,
ZHANG Hua ¹ ,
WANG Yulin ²

1.
School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China;
2.
Basic Medical College, Dalian Medical University, Dalian 116044, China

Received Date: 19 May 2017

To investigate the main chemical compositions of Verbena officinals L. extract, a qualitative high performance liquid chromatography-photodiode array-high resolution mass spectrometry (HPLC-PDA-HRMS) method was established. The structures of the compounds detected were identified by analyzing the chromatographic profiles and the corresponding mass spectra obtained by full scan and MSⁿ full scan. Twenty one compounds including iridoid glycosides, flavonoids, triterpenoids, phenylpropanoids and phenolic diterpenoids were identified, and six of them were not reported in other literatures about Verbena officinalis L. extract, such as carnosic acid, carnosol, rosmanol, isorosmanol, rosmarinic acid and acacetin-7-O-rutinoside. This method is simple, rapid, accurate and sensitive. It provides a reliable scientific basis for the identification of the authenticity and quality control of Chinese medicinal materials.
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沈阳化工大学材料科学与工程学院沈阳 110142