Citation: LI Huisi, HUANG Chaoqun, JIANG Qinting, ZHONG Yingying, ZHU Xiaoyu, CHEN Xiaomei, MO Weimin. Determination of five neonicotinoid pesticide residues in tea by online clean-up-liquid chromatography-tandem mass spectrometry[J]. Chinese Journal of Chromatography, ;2016, 34(3): 263-269. doi: 10.3724/SP.J.1123.2015.10003 shu

Determination of five neonicotinoid pesticide residues in tea by online clean-up-liquid chromatography-tandem mass spectrometry

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1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China;
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2. Zhejiang Entry-Exit Inspection and Quarantine Bureau, Hangzhou 310016, China;
3.
3. Ningbo Entry-Exit Inspection and Quarantine Bureau, Ningbo 315012, China

Corresponding author: HUANG Chaoqun,
Received Date: 7 October 2015

Fund Project: 国家质检总局科技计划项目(2015IK302) (2015IK302)宁波市重大课题(2007C10035). (2007C10035)

An online clean-up-liquid chromatography-tandem mass spectrometry method was developed for the determination of five neonicotinoid pesticides (imidacloprid, acetamiprid, thiamethoxam, thiacloprid and clothianidin) in tea. After rehydrated, extracted with acetonitrile, and cleaned-up online, the tea samples were determined by liquid chromatography-tandem mass spectrometry. The results indicated that the limits of quantification for the five neonicotinoid pesticides were 0.01 mg/kg, and the calibration curves were linear in the range of 1.0-10 μ g/L. The spiked recoveries for the five neonicotinoid pesticides from tea were in the range of 68.0%-113.2% with the relative standard deviations between 3.2% and 7.6%. This method is simple, rapid, accurate, and suitable for the simultaneous determination of the five neonicotinoid pesticides in tea.
- online clean-up,
- liquid chromatography-tandem mass spectrometry (LC-MS/MS),
- neonicotinoid pesticides,
- tea
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