Citation: CHENG Jianguo, LIU Kaiying, BAI Mindong, CHENG Chao, YU Yixuan, ZHOU Xinying. Determination of 2-methylisoborneol and geosmin in drinking water using headspace solid phase micro-extraction coupled with gas chromatography-mass spectrometry[J]. Chinese Journal of Chromatography, ;2015, 33(12): 1287-1293. doi: 10.3724/SP.J.1123.2015.08031 shu

Determination of 2-methylisoborneol and geosmin in drinking water using headspace solid phase micro-extraction coupled with gas chromatography-mass spectrometry

CHENG Jianguo ¹ ,
LIU Kaiying ^1,, ,
BAI Mindong ^1,2,, ,
CHENG Chao ¹ ,
YU Yixuan ¹ ,
ZHOU Xinying ¹

1.
1. Dalian Maritime University, Dalian 116026, China;

Corresponding author: LIU Kaiying, BAI Mindong,
Received Date: 26 August 2015

Fund Project: 国家科技支撑计划项目(2013BAC06B00) (2013BAC06B00)国家高技术研究发展计划("863"计划)项目(2012AA062609) ("863"计划)项目(2012AA062609)辽宁省重点实验室基础研究项目(LZ2015008) (LZ2015008)中央高校基本科研业务费专项资金(3132015140). (3132015140)

The odorous compounds of 2-methylisoborneol (2-MIB) and geosmin (GSM) heavily produced and released in water source are one of the most important factors leading to off-flavor emergencies and resident water consumption panic in drinking water. A headspace solid phase micro-extraction (HS-SPME) combined with gas chromatography-mass spectrometry (GC-MS) method was established for the simultaneous determination of these two trace earthy and musty compounds in reservoir water, reservoir soil and tap water. The conditions of HS-SPME, such as salt amount, extraction time and extraction temperature, were optimized based on orthogonal analysis. The qualitative and quantitative analyses of 2-MIB and GSM were carried out in the electron impact (EI)-selective ion scanning mode. The results showed that the linear relationship between peak area and concentration of 2-MIB and GSM was good enough (r²≥0.998) from 5 to 1000 ng/L, the limits of detection were 0.72 ng/L for 2-MIB, 0.34 ng/L for GSM and the limits of quantification were 2.40 ng/L for 2-MIB, 1.13 ng/L for GSM. When the target samples spiked in the range of 10-600 ng/L, the average recoveries of the target compounds were 93.6%-107.7% (RSD≤6.1%, n=6). Based on the above method, the target compounds in reservoir water, reservoir soil and tap water in a certain region of Liaoning Province were analyzed. The results showed that the two target odors in reservoir water were 3.0-3.6 ng/L. As for the extract of the soil around the reservoir, 2-MIB was 8.1 ng/L and GSM was 17.8 ng/L. The odorous substances were not detected in the tap water. This method is simple, accurate, reliable, highly sensitive and no need of organic solvents. And it is suitable for the detection of 2-MIB and GSM in drinking water.
- headspace solid phase micro-extraction (HS-SPME),
- gas chromatography-mass spectrometry (GC-MS),
- 2-methylisoborneol (2-MIB),
- geosmin (GSM),
- drinking water,
- orthogonal analysis
1. [1]
  [1] Sun D L, Yu J W, An W, et al. J Environ Sci, 2013, 25(3): 460
2. [2]
  [2] Klausen C, Nicolaisen M H, Strobel B W, et al. FEMS Microbiol Ecol, 2005, 52(2): 265
3. [3]
  [3] Li Z L, Hobson P, An W, et al. Water Res, 2012, 46(16): 5165
4. [4]
  [4] Korth W, Ellis J, Bowmer K. Water Sci Technol, 1992, 25(2): 115
5. [5]
  [5] Suffet I H, Schweitzer L, Khiari D. Rev Environ Sci Bio, 2004, 3: 3
6. [6]
  [6] GB 5749-2006
7. [7]
  [7] Bartels J H M, Brady B M, Suffet I H. J AWWA, 1987, 79(1): 26
8. [8]
  [8] Shin H S, Ahn H S. Chromatographia, 2004, 59: 107
9. [9]
  [9] Li F A. Water Technology (李福安. 供水技术), 2012, 6(4): 54
10. [10]
  [10] Manickum T, John W. Hydrol Current Res, 2012, 3(3): 1000134
11. [11]
  [11] Manickum T, John W, Malungana M P. Hydrol Current Res, 2011, 2(5): 121. DOI: 10.4172/2157-7587.1000121
12. [12]
  [12] Watson S B, Brownlee B, Satchwill T, et al. Water Res, 2000, 34(10): 2818
13. [13]
  [13] Wu D Y, Duirk S E. Chemosphere, 2013, 91: 1495
14. [14]
  [14] Wu J H, Wang Z H, Wang B, et al. Chinese Journal of Chromatography (吴金浩, 王召会, 王摆, 等. 色谱), 2013, 31(12): 1218
15. [15]
  [15] Yu J W, An W, Cao N, et al. J Environ Sci, 2014, 26: 1389
16. [16]
  [16] Ma X Y, Gao N Y, Li Q S, et al. Environmental Pollution and Control (马晓雁, 高乃云, 李青松. 环境污染与防治), 2006, 28(8): 631
17. [17]
  [17] Ding Z, Peng S F, Xia W W, et al. Int J Environ Anal Chem, 2014: 697260. http://dx.doi.org/10.1155/2014/697260
18. [18]
  [18] Li L, Song L R, Gan N Q, et al. Chinese Journal of Analytical Chemistry (李林, 宋立荣, 甘南琴, 等. 分析化学), 2005, 33(8): 1058
19. [19]
  [19] Peng S F, Ding Z, Xia W W, et al. J Anal Methods Chem, 2013: 340658. http://dx.doi.org/10.1155/2013/340658
20. [20]
  [20] Wei H R, Yi X B, Tan Y, et al. Chinese Journal of Chromatography (魏海蓉, 易锡斌, 谭钺, 等. 色谱), 2015, 33(6): 577
1. [1]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
2. [2]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
3. [3]
  Zhongbin Pan , Shijie Huang , Yunjie Luo , Hongzhen Xie . Design of a Comprehensive Experiment for Determining Permanganate Index (COD_Mn) in Drinking Water. University Chemistry, 2024, 39(7): 354-360. doi: 10.12461/PKU.DXHX202311040
4. [4]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
5. [5]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
6. [6]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
7. [7]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
8. [8]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
9. [9]
  Zian Lin , Yingxue Jin . Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry (MALDI-MS) for Disease Marker Screening and Identification: A Comprehensive Experiment Teaching Reform in Instrumental Analysis. University Chemistry, 2024, 39(11): 327-334. doi: 10.12461/PKU.DXHX202403066
10. [10]
  Gaoyan Chen , Chaoyue Wang , Juanjuan Gao , Junke Wang , Yingxiao Zong , Kin Shing Chan . Heart to Heart: Exploring Cardiac CT. University Chemistry, 2024, 39(9): 146-150. doi: 10.12461/PKU.DXHX202402011
11. [11]
  Yifeng TAN , Ping CAO , Kai MA , Jingtong LI , Yuheng WANG . Synthesis of pentaerythritol tetra(2-ethylthylhexoate) catalyzed by h-MoO₃/SiO₂. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2155-2162. doi: 10.11862/CJIC.20240147
12. [12]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
13. [13]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
14. [14]
  Jingming Li , Bowen Ding , Nan Li , Nurgul . Application of Comparative Teaching Method in Experimental Project Design of Instrumental Analysis Course: A Case Study in Chromatography Experiment Teaching. University Chemistry, 2024, 39(8): 263-269. doi: 10.3866/PKU.DXHX202312078
15. [15]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
16. [16]
  Min Gu , Huiwen Xiong , Liling Liu , Jilie Kong , Xueen Fang . Rapid Quantitative Detection of Procalcitonin by Microfluidics: An Instrumental Analytical Chemistry Experiment. University Chemistry, 2024, 39(4): 87-93. doi: 10.3866/PKU.DXHX202310120
17. [17]
  Wanqun Hu , Pingping Zhu , Yuan Zheng , Wanqun Zhang , Wei Shao , Hong Wu , Qiang Zhou , Kaiping Yang , Xiang Sheng . Design and Practice of Ideological and Political Case Study in Instrumental Analysis Experiment Course: the Extraction and Structural Identification of Artemisinin. University Chemistry, 2024, 39(2): 203-207. doi: 10.3866/PKU.DXHX202310062
18. [18]
  Liwei Wang , Guangran Ma , Li Wang , Fugang Xu . A Comprehensive Analytical Chemistry Experiment: Colorimetric Detection of Vitamin C Using Nanozyme and Smartphone. University Chemistry, 2024, 39(8): 255-262. doi: 10.3866/PKU.DXHX202312094
19. [19]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
20. [20]
  Haiyang Zhang , Yanzhao Dong , Haojie Li , Ruili Guo , Zhicheng Zhang , Jiangjiexing Wu . Exploring the Integration of Chemical Engineering Principle Experiment with Cutting-Edge Research Achievements. University Chemistry, 2024, 39(10): 308-313. doi: 10.12461/PKU.DXHX202405035

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(203)
HTML views(9)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142