Citation: XIE Shengming, LIU Hong, YANG Jiangrong, AI Ping, YUAN Liming. Single-handed helical framework material [{Cu(sala)}_n] incorporated peramylated β-cyclodextrin for improving gas chromatography enantioseparation[J]. Chinese Journal of Chromatography, ;2016, 34(1): 113-118. doi: 10.3724/SP.J.1123.2015.08001 shu

Single-handed helical framework material [{Cu(sala)}_n] incorporated peramylated β-cyclodextrin for improving gas chromatography enantioseparation

1.
1. School of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650500, China;
2.
2. Chuxiong Institute for Food and Drug Control, Chuxiong 675000, China;
3.
3. Dehong Vocational College, Dehong 678400, China

Corresponding author: YUAN Liming,
Received Date: 1 August 2015

Fund Project: 国家自然科学基金项目(21275126, 21365024) (21275126, 21365024)云南省应用基础研究计划项目(2013FB035). (2013FB035)

Metal-organic frameworks (MOFs) as a new generation of functional molecular materials, have broad application prospects in enantioselective catalysis and chiral separation areas due to their unusual properties, such as high surface area, rich topologies, permanent microporous, availability of outer-surface modification and so on. A single-handed helical three-dimensional metal-organic framework material [{Cu(sala)}_n] (H₂sala=N-(2-hydroxybenzyl)-L-alanine) was incorporated with peramylated β-cyclodextrin for the preparation of novel capillary gas chromatography stationary phase. To investigate whether the use of a chiral MOF can enhance enantioseparation on peramylated β-cyclodextrin, three chiral columns were fabricated using different stationary phases for comparison, including column A ([{Cu(sala)}_n]), column B (peramylated β-cyclodextrin) and column C ([{Cu(sala)}_n]+peramylated β-cyclodextrin). The results of comparing the resolving abilities of the three columns for the same chiral compounds demonstrated that column C showed better enantioselectivity and higher resolution. The use of MOF [{Cu(sala)}_n] can improve enantioseparation on peramylated β-cyclodextrin.
- gas chromatography (GC),
- metal-organic frameworks (MOFs),
- peramylated β-cyclodextrin,
- stationary phase,
- capillary column,
- chiral separation
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Single-handed helical framework material [{Cu(sala)}n] incorporated peramylated β-cyclodextrin for improving gas chromatography enantioseparation

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通讯作者: 陈斌, bchen63@163.com

Single-handed helical framework material [{Cu(sala)}_n] incorporated peramylated β-cyclodextrin for improving gas chromatography enantioseparation