Citation: NIU Zengyuan, LUO Xin, YE Xiwen, XIU Xiaoli, ZHANG Li, WANG Xin, CHEN Jing. Rapid screening and identification of 22 allergenic disperse dyes in ecological textiles by high performance liquid chromatography- linear ion trap/orbitrap mass spectrometry[J]. Chinese Journal of Chromatography, ;2015, 33(10): 1104-1109. doi: 10.3724/SP.J.1123.2015.04048 shu

Rapid screening and identification of 22 allergenic disperse dyes in ecological textiles by high performance liquid chromatography- linear ion trap/orbitrap mass spectrometry

NIU Zengyuan ^1,, ,
LUO Xin ¹ ,
YE Xiwen ¹ ,
XIU Xiaoli ^1,2 ,
ZHANG Li ^1,3 ,
WANG Xin ¹ ,
CHEN Jing ¹

1.
1. Technical Center for Inspection and Quarantine of Shandong Entry-Exit Inspection and Quarantine Bureau, Qingdao 266002, China;

Corresponding author: NIU Zengyuan,
Received Date: 28 April 2015

Fund Project: 质检公益性行业科研专项(201310062) (201310062)国家质检总局科技项目(2013IK015) (2013IK015)山东出入境检验检疫局科技项目(SK200994). (SK200994)

A rapid screening method based on high performance liquid chromatography-linear ion trap/orbitrap high-resolution mass spectrometry (HPLC-LTQ/Orbitrap MS) for 22 disperse dyes in ecological textiles has been established. The target compounds were extracted by pyridine/water (1:1, v/v) by shaking extraction in 90 ℃ water bath. The extracts were then separated by a CAPCELL PAK C₁₈ column (100 mm×2.0 mm, 5 μm) using gradient elution with acetonitrile-5 mmol/L ammonium acetate containing 0.01% (v/v) formic acid as mobile phases, and finally analyzed by HPLC-LTQ/Orbitrap in positive and negative ESI modes. The retention time and accurate mass of parent ion were used for fast screening of 22 disperse dyes, while the confirmatory analysis was obtained by fragments generated by collision-induced dissociation (CID) MS/MS. Target analysis exhibited high mass accuracy (< 5×10^-6). Each target showed a good linearity in its own concentration range and the correlation coefficient was higher than 0.99. The LOQs were 0.125-2.5 mg/kg. Except for Disperse Yellow 49, the average recoveries of most disperse dyes at three spiked levels were 65%-120%, and the relative standard deviations (n=6) were less than 15%. The method was applied for screening 40 different kinds of textiles, and Disperse Orange 37/76 was detected in one of them. With high selectivity and strong anti-jamming ability, this method is simple, rapid, accurate, and it can be used for the inspection of disperse dyes in textiles.
1. [1]
  [1] Oeko-Tex^®-International Association for Research and Testing in the Field of Textile Ecology. Oeko-Tex Standard 100. (2014-12-24). https://www.oeko-tex.com/en/manufactur- ers/manufacturers.xhtml
2. [2]
  [2] European Communities. Commission Decision of 9 July 2009 Establishing the Ecological Criteria for the Award of the Community Eco-label for Textile Products (2009/567/EC). (2009-07-09). http://eur-lex.europa.eu/search.html?qid=1435755118480&text=2009/567/EC&scope=EURLEX&type=quick&lang=en
3. [3]
  [3] BS EN 71-10: 2005
4. [4]
  [4] GB/T 20383-2006
5. [5]
  [5] García-Lavandeira J, Blanco E, Salgado C, et al. Talanta, 2010, 82: 261
6. [6]
  [6] Fang H W, Chen X, Lu Y P, et al. Journal of Instrumental Analysis (方慧文, 陈曦, 卢跃鹏, 等. 分析测试学报), 2010, 29(12): 1178
7. [7]
  [7] Zhao S H, Wu G, Wu J J, et al. Textile Standard and Quality (赵珊红, 吴刚, 吴俭俭, 等. 纺织标准与质量), 2010(2): 37
8. [8]
  [8] Yang C, Zhao J H, Wang J, et al. J Chromatogr A, 2013, 1300: 38
9. [9]
  [9] DeArmond P D, DiGoregorio A L. J Chromatogr A, 2013, 1305: 154
10. [10]
  [10] Schuhmann K, Herzog R, Schwudke D, et al. Anal Chem, 2011, 83: 5480
11. [11]
  [11] Guo C C, Shi F, Jiang S, et al. J Chromatogr B, 2014, 967: 174
12. [12]
  [12] Jia W, Chu X G, Ling Y, et al. J Chromatogr A, 2014, 1336: 67
13. [13]
  [13] Jia W, Chu X G, Ling Y, et al. J Chromatogr A, 2014, 1347: 122
14. [14]
  [14] Lehner S M, Neumann N K N, Sulyok M, et al. Food Addit Contam, 2011, 28: 1457
15. [15]
  [15] Quifer-Rada P, Vallverdú-Queralt A, Martínez-Huélamo M, et al. Food Chem, 2015, 169: 336
16. [16]
  [16] Zhang L, Luo X, Niu Z Y, et al. J Chromatogr A, 2015, 1386: 22
17. [17]
  [17] Xiu X L, Luo X, Niu Z Y, et al. Chinese Journal of Chromatography (修晓丽, 罗忻, 牛增元, 等. 色谱), 2013, 31(10): 961
18. [18]
  [18] Ye X W, Peng Y, Niu Z Y, et al. Chinese Journal of Chromatography (叶曦雯, 彭燕, 牛增元, 等. 色谱), 2014, 32(9): 1005
19. [19]
  [19] Peng Y, Ye X W, Niu Z Y, et al. Chinese Journal of Chromatography (彭燕, 叶曦雯, 牛增元, 等. 色谱), 2015, 33(4): 377
20. [20]
  [20] ISO 16373-2-2014
21. [21]
  [21] European Communities. Commission Decision of 12 August 2002 Implementing Council Directive 96/23/EC Concerning the Performance of Analytical Methods and the Interpretation of Results. Official Journal of the European Communities. 2002/657/EC. (2002-08-12). http://eur-lex.europa.eu/legal-content/EN/ALL/?uri=CELEX:32002D0657
22. [22]
  [22] Domènech A, Francisco N C, Palacios O, et al. J Chromatogr A, 2014, 1328: 16
23. [23]
  [23] Choi J H, Lamshöft M, Zühlke S, et al. Biomed Chromatogr, 2014, 28: 751
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