Citation: DAI Xuewei, WEI Biwen, WANG Xiuli, YU Wenjia, XU Yongwei. Determination of 18 polycyclic aromatic hydrocarbons in plastic products by ultra performance convergence chromatography[J]. Chinese Journal of Chromatography, ;2015, 33(10): 1059-1064. doi: 10.3724/SP.J.1123.2015.04047 shu

Determination of 18 polycyclic aromatic hydrocarbons in plastic products by ultra performance convergence chromatography

DAI Xuewei ¹ ,
WEI Biwen ¹ ,
WANG Xiuli ^1,, ,
YU Wenjia ¹ ,
XU Yongwei ²

1.
1. Shanghai Entry-Exit Inspection and Quarantine Bureau, Shanghai 200135, China;

Corresponding author: WANG Xiuli,
Received Date: 28 April 2015

A method for rapid determination of naphthalene, acenaphthylene, acenaphthene, fluorene, phenanthrene, anthracene, fluoranthene, pyrene, benzo(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(j)fluoranthene, benzo(e)pyrene, benzo(a)pyrene, indeno(1,2,3-cd)pyrene, dibenzo(a,h)anthracene, benzo(g,h,i)perylene in plastic products by ultra performance convergence chromatography (UPC²) coupled photodiode array detector (PAD) was developed. The 18 polycyclic aromatic hydrocarbons (PAHs) were successfully separated in less than 8.5 min on a Daicel IB-3 chiral column with a mobile phase of CO₂, the mobile-phase additive of methanol/acetonitrile (25:75, v/v) at column temperature of 40 ℃, and a back pressure of 15.17 MPa. There was a linear correlation between peak area and PAH concentration in the range of 0.05-50 mg/L (r≥0.9995) for each PAH. The limits of quantification (LOQs) (S/N> 10) were 0.05 mg/L. After ultrasonic-assisted extraction in toluene, the sample was analyzed by UPC²-PDA. The recoveries of PAHs spiked in plastic samples were from 78.3% to 117.6%, and the repeatabilities of peak areas for the 18 PAHs were less than 5% (RSD, n=5). The present UPC²-PDA method has the advantages of rapid speed, high resolution, and low organic reagent consumption.
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