Citation: DAI Xuewei, WEI Biwen, WANG Xiuli, YU Wenjia, XU Yongwei. Determination of 18 polycyclic aromatic hydrocarbons in plastic products by ultra performance convergence chromatography[J]. Chinese Journal of Chromatography, ;2015, 33(10): 1059-1064. doi: 10.3724/SP.J.1123.2015.04047 shu

Determination of 18 polycyclic aromatic hydrocarbons in plastic products by ultra performance convergence chromatography

DAI Xuewei ¹ ,
WEI Biwen ¹ ,
WANG Xiuli ^1,, ,
YU Wenjia ¹ ,
XU Yongwei ²

1.
1. Shanghai Entry-Exit Inspection and Quarantine Bureau, Shanghai 200135, China;

Corresponding author: WANG Xiuli,
Received Date: 28 April 2015

A method for rapid determination of naphthalene, acenaphthylene, acenaphthene, fluorene, phenanthrene, anthracene, fluoranthene, pyrene, benzo(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(j)fluoranthene, benzo(e)pyrene, benzo(a)pyrene, indeno(1,2,3-cd)pyrene, dibenzo(a,h)anthracene, benzo(g,h,i)perylene in plastic products by ultra performance convergence chromatography (UPC²) coupled photodiode array detector (PAD) was developed. The 18 polycyclic aromatic hydrocarbons (PAHs) were successfully separated in less than 8.5 min on a Daicel IB-3 chiral column with a mobile phase of CO₂, the mobile-phase additive of methanol/acetonitrile (25:75, v/v) at column temperature of 40 ℃, and a back pressure of 15.17 MPa. There was a linear correlation between peak area and PAH concentration in the range of 0.05-50 mg/L (r≥0.9995) for each PAH. The limits of quantification (LOQs) (S/N> 10) were 0.05 mg/L. After ultrasonic-assisted extraction in toluene, the sample was analyzed by UPC²-PDA. The recoveries of PAHs spiked in plastic samples were from 78.3% to 117.6%, and the repeatabilities of peak areas for the 18 PAHs were less than 5% (RSD, n=5). The present UPC²-PDA method has the advantages of rapid speed, high resolution, and low organic reagent consumption.
1. [1]
  [1] ZEK 01.4-08
2. [2]
  [2] Commission Regulation (EU) No 1272/2013
3. [3]
  [3] United States Environmental Protection Agency (EPA) No 440479029b/1979
4. [4]
  [4] SN/T 1877.4-2007
5. [5]
  [5] SN/T 1877.6-2009
6. [6]
  [6] SN/T 1877.2-2007
7. [7]
  [7] SN/T 3338-2012
8. [8]
  [8] Simko P. J Chromatogr B, 2002, 770: 3
9. [9]
  [9] Plaza-Bolaños P, Frenich A G, Vidal J L M. J Chromatogr A, 2010, 1217: 6303
10. [10]
  [10] Yang Z J, Wang C Y, Xu R, et al. Paper Chemicals (杨左军, 王成云, 徐嵘, 等. 造纸化学品), 2014, 26(1): 9
11. [11]
  [11] Zhang Y, Du Z X, Yu W L. Chinese Journal of Chromatography (张云, 杜振霞, 于文莲. 色谱), 2014, 32(1): 52
12. [12]
  [12] Huang C. Environmental Chemistry (黄春. 环境化学), 2012, 31(8): 1287
13. [13]
  [13] Lin C H, Yan N, Xu Z H, et al. Journal of Instrumental Analysis (林春花, 严楠, 许招会, 等. 分析测试学报), 2014, 33(11): 1322
14. [14]
  [14] Tang J, Ding Y C, Cao X Z, et al. Chinese Journal of Chromatography (汤娟, 丁友超, 曹锡忠, 等. 色谱), 2014, 32(11): 1230
15. [15]
  [15] Zhou W, Wang B, Liu Q Q, et al. Chinese Journal of Analytical Chemistry (周围, 王波, 刘倩倩, 等. 分析化学), 2015, 43(1): 115
16. [16]
  [16] Li Z H, Wu S B, Liu S S, et al. Chinese Journal of Analytical Chemistry (李中皓, 吴帅宾, 刘珊珊, 等. 分析化学), 2013, 41(12): 1817
1. [1]
  Yifan Xie , Liyun Yao , Ruolin Yang , Yuxing Cai , Yujie Jin , Ning Li . Exploration and Practice of Online and Offline Hybrid Teaching Mode in High-Performance Liquid Chromatography Experiment. University Chemistry, 2025, 40(11): 100-107. doi: 10.12461/PKU.DXHX202412133
2. [2]
  Conghao Shi , Ranran Wang , Juli Jiang , Leyong Wang . The Illustration on Stereoisomers of Macrocycles Containing Multiple Chiral Centers via Tröger Base-based Macrocycles. University Chemistry, 2024, 39(7): 394-397. doi: 10.3866/PKU.DXHX202311034
3. [3]
  Tong Wang , Liangyu Hu , Shiqi Chen , Xinqiang Fu , Rui Wang , Kun Li , Shuangyan Huan . Determination of Benzenediol Isomers in Cosmetics Using High-Performance Liquid Chromatography Empowered by “Mathematical Separation”. University Chemistry, 2026, 41(1): 9-19. doi: 10.12461/PKU.DXHX202503128
4. [4]
  Chenfei Li , Xu Han , Qimeng Zhang , Ben Zhang , Xinyao Huang , Mingxiao Deng , Caixia Zheng , Haizhu Sun . Measurement of Stress-Strain Curves of Polymeric Materials Using a Non-Contact Displacement Detector. University Chemistry, 2026, 41(1): 179-187. doi: 10.12461/PKU.DXHX202505101
5. [5]
  Binbin Liu , Yang Chen , Tianci Jia , Chen Chen , Zhanghao Wu , Yuhui Liu , Yuhang Zhai , Tianshu Ma , Changlei Wang . Hydroxyl-functionalized molecular engineering mitigates 2D phase barriers for efficient wide-bandgap and all-perovskite tandem solar cells. Acta Physico-Chimica Sinica, 2026, 42(1): 100128-0. doi: 10.1016/j.actphy.2025.100128
6. [6]
  Runjie Li , Hang Liu , Xisheng Wang , Wanqun Zhang , Wanqun Hu , Kaiping Yang , Qiang Zhou , Si Liu , Pingping Zhu , Wei Shao . 氨基酸的衍生及手性气相色谱分离创新实验. University Chemistry, 2025, 40(6): 286-295. doi: 10.12461/PKU.DXHX202407059
7. [7]
  Tinghui Hu , Junwen Long , Yi Long , Xuanhe Liu . Plastic Disillusionment. University Chemistry, 2025, 40(7): 249-254. doi: 10.12461/PKU.DXHX202409004
8. [8]
  Mengyang LI , Hao XU , Zhonghao NIU , Chunhua GONG , Weihui ZHONG , Jingli XIE . Highly effective catalytic synthesis of β-amino alcohols by using viologen-polyoxometalate hybrid materials. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1294-1300. doi: 10.11862/CJIC.20250080
9. [9]
  Li'na ZHONG , Jingling CHEN , Qinghua ZHAO . Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 709-718. doi: 10.11862/CJIC.20240280
10. [10]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
11. [11]
  Ruolin CHENG , Yue WANG , Xiyao NIU , Huagen LIANG , Ling LIU , Shijian LU . Efficient photothermal catalytic CO₂ cycloaddition over W₁₈O₄₉/rGO composites. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1276-1284. doi: 10.11862/CJIC.20240424
12. [12]
  Jiarui Wu , Gengxin Wu , Yan Wang , Yingwei Yang . Crystal Engineering Based on Leaning Towerarenes. University Chemistry, 2024, 39(3): 58-62. doi: 10.3866/PKU.DXHX202304014
13. [13]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
14. [14]
  Shunü Peng , Huamin Li , Zhaobin Chen , Yiru Wang . Simultaneous Application of Multiple Quantitative Analysis Methods in Gas Chromatography for the Determination of Active Ingredients in Traditional Chinese Medicine Preparations. University Chemistry, 2025, 40(10): 243-249. doi: 10.12461/PKU.DXHX202412043
15. [15]
  Shengjuan Huo , Xiaoyan Zhang , Xiangheng Li , Xiangning Li , Tianfang Chen , Yuting Shen . Unveiling the Marvels of Titanium: Popularizing Multifunctional Colored Titanium Product Films. University Chemistry, 2024, 39(5): 184-192. doi: 10.3866/PKU.DXHX202310127
16. [16]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
17. [17]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
18. [18]
  Qin Hou , Jiayi Hou , Aiju Shi , Xingliang Xu , Yuanhong Zhang , Yijing Li , Juying Hou , Yanfang Wang . Preparation of Cuprous Iodide Coordination Polymer and Fluorescent Detection of Nitrite: A Comprehensive Chemical Design Experiment. University Chemistry, 2024, 39(8): 221-229. doi: 10.3866/PKU.DXHX202312056
19. [19]
  Yuai Duan , Xuanyu Gan , Yao Fu , Yingjie Cao , Hongliang Han , Zhanfang Ma . Application and Innovative Design of Digital Technology in the Preparation Experiment of Cis(Trans)-Diglycine Copper Complexes. University Chemistry, 2026, 41(1): 373-381. doi: 10.12461/PKU.DXHX202504048
20. [20]
  Shumin Zhang , Yaqi Wang , Zelin Wang , Libo Wang , Changsheng An , Difa Xu . Ultrafast electron transfer at the ZIS_1−x/UCN S-scheme interface enables efficient H₂O₂ photosynthesis coupled with tetracycline degradation. Acta Physico-Chimica Sinica, 2025, 41(11): 100136-0. doi: 10.1016/j.actphy.2025.100136

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(477)
HTML views(28)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142